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品質等級
化驗
97%
mp
196-199 °C (lit.)
溶解度
ethyl acetate: soluble 25 mg/mL, clear, yellow to orange
SMILES 字串
N1c2ccccc2C=Cc3ccccc13
InChI
1S/C14H11N/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)15-13/h1-10,15H
InChI 密鑰
LCGTWRLJTMHIQZ-UHFFFAOYSA-N
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一般說明
5H-二苯并[b,f]吖庚因是一种具有七元环的三环类胺，常称为亚氨基芪。它可用作合成多种抗痉挛药物的中间体或起始材料。
應用
5H-二苯并[b,f]氮杂卓可用于：
- 作为原料制备重要的二苯并氮杂卓-哒嗪衍生物。
- 合成氨基苯酚衍生物制备中的关键中间体 3-氯-1-(5H-二苯并[b,f]氮杂卓-5基)丙烷-1-酮。
- 合成二苯并氮杂卓衍生物。
- 作为原料合成用于制备铑（I）配合物的烯类多齿配体。
生化／生理作用
2-（溴甲基）萘是一种荧光烷基溴。它通过酶水解使聚对苯二甲酸乙二醇酯表面形成的游离羧基酯化。它在P4S10/酰基胞苷反应中充当有机亲电子试剂。
訊號詞
Warning
危險聲明
危險分類
Acute Tox. 4 Oral - Aquatic Chronic 2
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 2
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis and Calorimetry of Some Derivatives of Dibenzazepine
Analytical Calorimetry (1970)
Synthesis and Calorimetry of Some Derivatives of Dibenzazepine.
Gipstein E, et al.
Analytical Calorimetry, 127-134 (1970)
Kuppuswamy Arumugam et al.
Inorganic chemistry, 46(8), 3283-3288 (2007-03-16)
The reaction of P4S10 with acyloins, RC(O)CH(OH)R, in refluxing dioxane, followed by the addition of alkylating agents, forms dithiolene thiophosphoryl thiolate compounds, (R2C2S2)P(S)(SR'), which are readily isolated and purified. The compounds that have been prepared and identified spectroscopically are those
S M Furst et al.
Biochemical pharmacology, 45(6), 1267-1275 (1993-03-24)
Carbamazepine is an anticonvulsant which is associated with a significant incidence of hypersensitivity reactions including agranulocytosis. We have postulated that many drug hypersensitivity reactions, especially agranulocytosis and lupus, are due to reactive metabolites generated by the myeloperoxidase (MPO) (EC 1.11.1.7)
A Varenne et al.
Journal of immunological methods, 186(2), 195-204 (1995-10-26)
As part of our ongoing work to extend the range of applications of the non-isotopic carbonyl metalloimmunoassay (CMIA), previously developed in our laboratory, we describe here the first CMIA study of carbamazepine. The CMIA method uses a metal carbonyl complex
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