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Merck

142670

Sigma-Aldrich

氯甲基乙醚

95%

别名:

(Chloromethoxy)ethane, Ethoxychloromethane, Ethoxymethyl chloride, Ethyl chloromethyl ether

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About This Item

线性分子式:
C2H5OCH2Cl
CAS号:
分子量:
94.54
EC號碼:
MDL號碼:
分類程式碼代碼:
12352101
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

95%

形狀

liquid

折射率

n20/D 1.404 (lit.)

bp

82 °C (lit.)

密度

1.019 g/mL at 25 °C (lit.)

官能基

chloro
ether

儲存溫度

2-8°C

SMILES 字串

CCOCCl

InChI

1S/C3H7ClO/c1-2-5-3-4/h2-3H2,1H3

InChI 密鑰

FCYRSDMGOLYDHL-UHFFFAOYSA-N

應用

氯甲基乙醚可用于制备:
  • 6-苄基-1-(乙氧基甲基)-5-碘嘧啶-2,4(1H,3H)-二酮,其是MKC-442类似物制备中的一种关键中间体。
  • 通过与乙二醛-双-[(R)-1-(2-萘基)乙基]亚胺反应生成醇的酰化催化剂1,3-双-[(R)-1-(2-萘基)乙基氯化咪唑。

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

66.2 °F - closed cup

閃點(°C)

19 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

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K Takahashi et al.
Mutation research, 156(3), 153-161 (1985-06-01)
The mutagenic characteristics of formaldehyde on bacteria were examined. All the tester strains of Escherichia coli deficient in DNA-repair enzymes tested in the present study were significantly more sensitive to the killing effect of formaldehyde than the corresponding wild-type strain.
Chiral N-heterocyclic carbenes as asymmetric acylation catalysts
Suzuki Y, et al.
Tetrahedron, 62(2-3), 302-310 (2006)
bis(Chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 10, 56-57 (2004-08-24)
Tadeusz J Szalaty et al.
International journal of biological macromolecules, 119, 431-437 (2018-07-29)
In this research we use ionic liquids in combination with mild process conditions to provide a selective increase in the content of carbonyl groups in the kraft lignin structure. Such modification can improve the properties of the pristine biopolymer. In
Three Routes for the Synthesis of 6-Benzyl-1-ethoxymethyl-2, 4-dioxo-1, 2, 3, 4-tetrahydropyrimidine-5-carbaldehyde
Petersen L, et al.
Synthesis, 2001(04), 0559-0564 (2001)

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