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品質等級
產品線
ReagentPlus®
化驗
99%
形狀
powder
折射率
n20/D 1.39 (lit.)
bp
163.5 °C (lit.)
mp
50-54 °C (lit.)
溶解度
ethanol: soluble 50 mg/mL, clear to very slightly hazy, colorless
密度
1.148 g/mL at 25 °C (lit.)
SMILES 字串
COC(=O)C(=O)OC
InChI
1S/C4H6O4/c1-7-3(5)4(6)8-2/h1-2H3
InChI 密鑰
LOMVENUNSWAXEN-UHFFFAOYSA-N
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一般說明
草酸二甲酯经过 Cu/SiO2 催化的氢化反应,得到乙二醇。它经过Ag/SiO2 催化的选择性气相加氢反应,得到相应的醇。
應用
草酸二甲酯(DMO)被用作直接氧化燃料电池中的替代燃料。DMO被用于研究在惰性气体低温基质中分离所得DMO的IR光谱。
法律資訊
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
167.0 °F - closed cup
閃點(°C)
75 °C - closed cup
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
其他客户在看
A1h NMR Pulse Gradient Spin-Echo (PGSE) Mass Transport Study of Dimethyl Oxalate and Ethylene Glycol: New Fuels for the DOFC.
Electrochemical and Solid-State Letters, 12(3), 525-528 (2000)
Molecular structure and infrared spectra of dimethyl oxalate.
Physical Chemistry Chemical Physics, 4(6), 1014-1020 (2002)
Chemical communications (Cambridge, England), 49(45), 5195-5197 (2013-05-02)
The variation of the supports on the Cu/SiO2 catalyst plays an important role in the catalytic performance for hydrogenation of dimethyl oxalate. The loss of silica in the form of tetramethoxysilane from the support under the reaction conditions is responsible
Chemical communications (Cambridge, England), 46(24), 4348-4350 (2010-05-14)
Ag/SiO(2) prepared by a sol-gel process is highly effective for selective gas-phase hydrogenation of dimethyl oxalate to corresponding alcohols. The catalysts are of great potential as industrially viable and novel catalysts for the production of methyl glycolate and ethylene glycol.
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