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117714

Sigma-Aldrich

3-甲氧基苯甲酸

ReagentPlus®, 99%

别名:

间甲基水杨酸, 间茴香酸

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About This Item

线性分子式:
CH3OC6H4CO2H
CAS号:
586-38-9
分子量:
152.15
Beilstein:
508838
EC號碼:
209-574-9
MDL號碼:
MFCD00002499
分類程式碼代碼:
12352100
PubChem物質ID:
24847342
NACRES:
NA.22

品質等級

100

產品線

ReagentPlus®

化驗

99%

bp

170-172 °C/10 mmHg (lit.)

mp

105-107 °C (lit.)

溶解度

95% ethanol: soluble 50 mg/mL, clear, colorless to faintly yellow

官能基

carboxylic acid

SMILES 字串

COc1cccc(c1)C(O)=O

InChI

1S/C8H8O3/c1-11-7-4-2-3-6(5-7)8(9)10/h2-5H,1H3,(H,9,10)

InChI 密鑰

XHQZJYCNDZAGLW-UHFFFAOYSA-N

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一般說明

3-甲氧基苯甲酸是天然产物合成中的重要中间体。

應用

3-甲氧基苯甲酸用于合成和表征铕（III）和钆（III）的 3-甲氧基苯甲酸酯。将其用于将芳族羧酸转化为甲酯并使用硼氢化钠-THF-甲醇系统还原成相应的伯醇。

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析证书(COA)

Lot/Batch Number
STBF3336V
06210PE
06929HE
08317BE
10612TD

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Synthesis, characterization and thermal behaviour of solid-state compounds of europium (III) and gadolinium (III) 3-methoxybenzoate.
Dametto PR, et al.
Journal of Thermal Analysis and Calorimetry, 97(2), 765-768 (2009)
Sodium borohydride reduction of aromatic carboxylic acids via methyl esters.
Saeed A and Ashraf Z.
Journal of Chemical Sciences (Bangalore), 118(5), 419-423 (2006)
N Dodoff et al.
Journal of inorganic biochemistry, 54(3), 221-233 (1994-05-15)
The complexes [Pt(bah)2X2], [Pt(NH3)(bah)Cl2].0.5H2O, [Pt(mbah)2X2], and [Pt(NH3)(mbah)Cl2] (bah = benzoic acid hydrazide, mbah = 3-methoxybenzoic acid hydrazide; X = Cl, Br, I) have been prepared and characterized by elemental analysis, electric conductivity, IR, 1H NMR, and electronic spectra. A cis-square
K A DeWeerd et al.
Applied and environmental microbiology, 54(5), 1237-1242 (1988-05-01)
O-methyl substituents of aromatic compounds can provide C1 growth substrates for facultative and strict anaerobic bacteria isolated from diverse environments. The mechanism of the bioconversion of methoxylated benzoic acids to the hydroxylated derivatives was investigated with a model substrate and
Thi-Huu Nguyen et al.
Organic letters, 7(12), 2445-2448 (2005-06-04)
[reaction: see text] If employed in THF at 0 degrees C, LTMP metalates meta-anisic acid at the doubly activated position. In contrast, n-BuLi/t-BuOK deprotonates position C-4 preferentially at low temperature. Functionalization at C-6 requires protection of the C-2 site beforehand.
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