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![二[2-(甲基丙烯酰氧基)乙基]磷酸酯](/deepweb/assets/sigmaaldrich/product/structures/128/336/4e7a3e38-338c-423e-95b8-70d9d1f8e121/640/4e7a3e38-338c-423e-95b8-70d9d1f8e121.png)
品質等級
化驗
97%
折射率
n20/D 1.429 (lit.)
bp
202 °C (lit.)
密度
1.068 g/mL at 25 °C (lit.)
官能基
phosphonate
儲存溫度
2-8°C
SMILES 字串
CCOP(=O)(OCC)C=C
InChI
1S/C6H13O3P/c1-4-8-10(7,6-3)9-5-2/h6H,3-5H2,1-2H3
InChI 密鑰
DREPONDJUKIQLX-UHFFFAOYSA-N
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應用
乙烯基膦酸二乙酯已用于制备N-烷基-2-氨基乙基膦酸二乙酯。
乙烯基膦酸二乙酯（DEVP）可用作合成以下物质的前体：
它也可以用作单体单元，用于通过镧系元素络合物制备高分子量聚合物聚（二乙基乙烯基膦酸酯）。{18）
- α, β与芳基硼酸进行Pd催化的Mizoroki−Heck反应生成不饱和膦酸酯。
- 通过氮杂迈克尔（aza-Michael）反应与伯胺和仲胺缩合生成2-（芳基氨基）乙基膦酸酯。
它也可以用作单体单元，用于通过镧系元素络合物制备高分子量聚合物聚（二乙基乙烯基膦酸酯）。{18）
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
230.0 °F - closed cup
閃點（°C）
110 °C - closed cup
個人防護裝備
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Poly (vinylphosphonate) s synthesized by trivalent cyclopentadienyl lanthanide-induced group transfer polymerization
Salzinger S, et al.
Macromolecules, 44(15), 5920-5927 (2011)
Joachim E Klee et al.
Beilstein journal of organic chemistry, 5, 72-72 (2009-01-01)
Novel N-alkyl-N-(phosphonoethyl) substituted mono-, bis- and tris(meth)acrylamides 3 were synthesized by two different three-step reactions and characterized by IR, (1)H NMR and (13)C NMR spectroscopy as well as refractive index and viscosity. The phosphonoethyl substituted (meth)acrylamide monomers show improved hydrolytic
Convenient synthesis of α, β-unsaturated phosphonates via a Mizoroki-Heck reaction of arylboronic acids with diethyl vinylphosphonate
Kabalka GW, et al.
Tetrahedron Letters, 45(24), 4685-4687 (2004)
Synthesis of 2-(arylamino) ethyl phosphonic acids via the aza-Michael addition on diethyl vinylphosphonate
Orm Nadine B, et al.
Tetrahedron, 69(1), 115-121 (2013)
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