537713

4-Methyl-2-pentanon

≥99%

• Synonym(e): Isobutylmethylketon, Isopropylaceton, MIBK, Methylisobutylketon
• Lineare Formel: (CH₃)₂CHCH₂COCH₃
• CAS-Nummer: 108-10-1
• Molekulargewicht: 100.16
• Beilstein: 605399
• EG-Nummer: 203-550-1
• MDL-Nummer: MFCD00008938
• UNSPSC-Code: 12352115
• PubChem Substanz-ID: 329757992
• NACRES: NA.21
• bp: 117-118 °C

Eigenschaften

• Dampfdichte: 3.5 (vs air)
• Qualitätsniveau: 100
• Dampfdruck: 15.7 mmHg
• Assay: ≥99%
• Form: liquid
• Selbstzündungstemp.: 840 °F
• Expl.-Gr.: 1.2-8 %, 93 °F
• Verunreinigungen: ≤0.1000% (water)
• Brechungsindex: n20/D 1.395 (lit.)
• bp: 117-118 °C
• mp (Schmelzpunkt): −80 °C (lit.)
• Löslichkeit: water: soluble 20 g/L
• Dichte: 0.801 g/mL at 25 °C (lit.)
• SMILES String: CC(C)CC(C)=O
• InChI: 1S/C6H12O/c1-5(2)4-6(3)7/h5H,4H2,1-3H3
• InChIKey: NTIZESTWPVYFNL-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

4-Methyl-2-pentanone (Methyl isobutyl ketone, MIBK), an aliphatic ketone, is commonly used as an organic solvent. It is generally used as an extractant in atomic absorption spectrometry. Preparation of MIBK using 2-propanol as the precursor has been reported with yield as high as 25%. The rate constant for the reaction between OH radical and MIBK was found to be 1.40 ± 0.07×10¹¹cm³molecule^-1s^-1. The kinetics and mechanism of photochemical reaction of MIBK in n-hexane solution has been studied. The microwave spectrum of MIBK has been recorded to obtain its rotational constants and centrifugal distortion constants.

Anwendung

4-Methyl-2-pentanone may be used to prepare (R)-(-)-4-methyl-2-pentanol via asymmetric hydrogenation in the presence of silica-supported starch-polysulfosiloxane-platinum complex (SiO₂-ST-Si-S-Pt).

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS07
• Signalwort: Danger
• H-Sätze: H225,H319,H332,H336,H351
• P-Sätze: P202 - P210 - P233 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
• Gefahreneinstufungen: Acute Tox. 4 Inhalation - Carc. 2 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• Zielorgane: Central nervous system
• Zusätzliche Gefahrenhinweise: EUH066
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 1
• Flammpunkt (°F): 57.2 °F - closed cup
• Flammpunkt (°C): 14 °C - closed cup