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Key Documents

24308

Supelco

β-DEX 325

L × I.D. 30 m × 0.25 mm, df 0.25 μm

Sinonimo/i:

β-DEX 325, 30M .25MM .25UM

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About This Item

Codice UNSPSC:
41115710
eCl@ss:
32119290

Materiali

fused silica

Livello qualitativo

Descrizione

GC capillary column

Parametri

30-230 °C temperature

Beta

250

df

0.25 μm

tecniche

gas chromatography (GC): suitable

Lungh. × D.I.

30 m × 0.25 mm

Gruppo funzionale matrice

non-bonded; 25% 2,3-di-O-methyl-6-O-TBDMS-β-cyclodextrin in SPB-20 poly(20% phenyl/80% dimethylsiloxane) phase

applicazioni

agriculture
chemicals and industrial polymers
cleaning products
clinical
cosmetics
environmental
flavors and fragrances
food and beverages
forensics and toxicology
life science and biopharma
personal care
pharmaceutical (small molecule)

Tipo di colonna

capillary chiral

Tecnica di separazione

chiral

Descrizione generale

The chiral stationary phase in β-DEX 325 columns contains 2,3-di-O-methyl-6-0-TBDMS-β-cyclodextrin embedded in an intermediate polarity phase. The Supelco β-DEX 325 is similar in both chemistry and use to the CHIRALDEX B-DM phase, the main difference being the concentration of the dimethyl-derivatized cyclodextrin that is doped into the polysiloxane carrier.

Applicazioni

ß-DEX-325 column was used in gas-liquid chromatography (GLC), for determination of (R)-1-O-acetyl-2-ethyl-1,3-propanediol, formed from 2-Ethyl-1,3-propanediol 1 and its related di-O-acetate, by partial chemoenzymatic acetylation and deacetylation, by Pseudomonas fluorescens lipase. ß -Dex-325 capillary column was also used for resolving 8-acetoxylinalool enantiomers, in an experimental study done in order to study the origin of the enantioselectivity in the biosynthesis of the lilac compounds in Actinidia arguta flowers.

Resistenza chim/fis

Temp. Limits:
  • 30 °C to 230 °C

Altre note

We offer a variety of chromatography accessories including analytical syringes

Note legali

DEX is a trademark of Sigma-Aldrich Co. LLC

Applicazioni

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A J Matich et al.
Phytochemistry, 68(13), 1746-1751 (2007-05-01)
Biosynthesis of lilac compounds in 'Hortgem Tahi' kiwifruit (Actinidia arguta) flowers was investigated by treating inflorescences with d(5)-linalool. The incorporation of the deuterium label into 8-hydroxylinalool, 8-oxolinalool, the lilac aldehydes, alcohols, and alcohol epoxides was followed by GC-MS and enantioselective
Chiral building-blocks by chemoenzymatic desymmetrization of 2-ethyl-1, 3-propanediol for the preparation of biologically active natural products.
Isidoro I
Tetrahedron Asymmetry, 10 (3), 449-455 (1999)

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