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Documenti fondamentali

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221937

Sigma-Aldrich

Ammonium iodide

greener alternative

ACS reagent, ≥99%

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About This Item

Formula condensata:
NH4I
Numero CAS:
12027-06-4
Peso molecolare:
144.94
Numero CE:
234-717-7
Numero MDL:
MFCD00011424
Codice UNSPSC:
12352300
eCl@ss:
38050607
ID PubChem:
329752286
Saggio:
≥99%
Grado:
ACS reagent
Stato:
powder or crystals

Grado

ACS reagent

Livello qualitativo

200

Tensione di vapore

1 mmHg ( 210.9 °C)

Saggio

≥99%

Stato

powder or crystals

Caratteristiche più verdi

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Impurezze

≤0.005% insolubles

Residuo alla calcinazione

≤0.05%

pH

4.5-6.5 (25 °C, 50 g/L)

Anioni in tracce

Cl- and Br-: ≤0.005%
phosphate (PO43-): ≤0.001%
sulfate (SO42-): ≤0.05%

Cationi in tracce

Ba: ≤0.002%
Fe: ≤5 ppm
heavy metals (as Pb): ≤0.001%

Categoria alternativa più verde

Aligned

Stringa SMILE

N.I

InChI

1S/HI.H3N/h1H;1H3
UKFWSNCTAHXBQN-UHFFFAOYSA-N

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Descrizione generale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is used as a ntrogen source for syntheis of many heterocyclic compounds and is also used as a catalyst or redox catalyst in some reactions. Click here for more information.
The high yield and regioselective conversion of an unactivated aziridine to an oxazolidinone using carbon dioxide with ammonium iodide as the catalyst

Applicazioni

Catalyst for mild, efficient, and greener dethioacetalization.
Catalyst for mild, efficient, and greener dethioacetalization.

Chemoselective Bromination of Active Methylene and Methyne Compounds by Potassium Bromide, Hydrochloric Acid and Hydrogen Peroxide

Pittogrammi

Health hazard
GHS08

Avvertenze

Danger

Indicazioni di pericolo

H372

Classi di pericolo

STOT RE 1 Oral

Organi bersaglio

Thyroid

Codice della classe di stoccaggio

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

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Certificati d'analisi (COA)

Lot/Batch Number
MKCQ5415
MKCP9379
MKCN4442
MKCK7658
MKCK1508

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Jinho Kim et al.
Organic letters, 14(15), 3924-3927 (2012-07-17)
Copper-mediated regioselective cyanation of indoles and 2-phenylpyridines was developed by using ammonium iodide and DMF as the combined source of a cyano unit under "Pd-free" conditions. Mechanistic studies indicate that the reaction of indoles proceeds through a two-step sequence: electrophilic
Xiaofang Gao et al.
Chemical communications (Cambridge, England), 51(1), 210-212 (2014-11-20)
A novel ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones is described. The process proceeded smoothly under metal-free conditions with high stereoselectivity and good functional group tolerance. The reaction mechanism was revealed
Simple and regioselective oxyiodination of aromatic compounds with ammonium iodide and Oxone.
Mohan KVVK, et al.
Tetrahedron Letters, 45(43), 8015-8018 (2004)
Low-Frequency Vibrations in Ammonium Iodide and Ammonium Bromide.
Durig JR and Antion DJ.
J. Chem. Phys. , 51(9), 3639-3647 (1969)
Jinho Kim et al.
Journal of the American Chemical Society, 134(5), 2528-2531 (2012-01-28)
The cyanation of aromatic boronic acids, boronate esters, and borate salts was developed under copper-mediated oxidative conditions using ammonium iodide and DMF as the source of nitrogen and carbon atom of the cyano unit, respectively. The procedure was successfully extended
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