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209619

Sigma-Aldrich

Potassium carbonate

ACS reagent, ≥99.0%

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About This Item

Formula condensata:
K2CO3
Numero CAS:
Peso molecolare:
138.21
Beilstein:
4267587
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
ID PubChem:
NACRES:
NA.21

Grado

ACS reagent

Livello qualitativo

Saggio

≥99.0%

Forma fisica

powder or crystals

Impurezze

≤0.004% S compounds as (SO42-)
≤0.005% silica
≤0.01% insolubles

pH

11-13 (25 °C, 138 g/L)

Punto di fusione

891 °C (lit.)

Anioni in tracce

chloride (Cl-): ≤0.003%
phosphate (PO43-): ≤0.001%

Cationi in tracce

Ca: ≤0.005%
Fe: ≤5 ppm
Mg: ≤0.002%
Na: ≤0.02%
heavy metals: ≤5 ppm (by ICP-OES)

Stringa SMILE

[K+].[K+].[O-]C([O-])=O

InChI

1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
BWHMMNNQKKPAPP-UHFFFAOYSA-L

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Descrizione generale

Potassium carbonate is an inorganic base. It participates as a base in the palladacycle catalyzed Heck reaction of chlorobenzene with styrene. Addition of amino acids (glycine, sarcosine and proline) to K2CO3 (solvent) promotes the absorption of CO2.

Applicazioni

Potassium carbonate has been used in the preparation of disulfonated bis[4-(3-aminophenoxy)phenyl]sulfone, a disulfonated diamine monomer.
It may be used in the following studies:
  • As a reagent in the synthesis of polysubstituted iodobenzene derivatives.
  • As a base for the synthesis of high molecular weight homopolymers and copolymers derived from various bisphenols.
  • As a base for the Suzuki coupling of aryl halides with aryl boronic acids.
  • The Heck reaction of styrene and bromobenzene.

Note legali

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Pittogrammi

Exclamation mark

Avvertenze

Warning

Indicazioni di pericolo

Classi di pericolo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

13 - Non Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


Certificati d'analisi (COA)

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I clienti hanno visto anche

A kinetic study of CO2 capture with potassium carbonate solutions promoted with various amino acids: glycine, sarcosine and proline.
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Polyamide interfacial composite membranes prepared from m-phenylene diamine, trimesoyl chloride and a new disulfonated diamine.
Xie W, et al.
Journal of Membrane Science, 403, 152-161 (2012)
Chelating N-heterocyclic carbene ligands in palladium-catalyzed Heck-type reactions.
Herrmann WA, et al.
Journal of Organometallic Chemistry, 557(1), 93-96 (1998)
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Organic letters, 17(7), 1644-1647 (2015-03-21)
The cobalt-catalyzed Diels-Alder reaction of trimethylsilyl-substituted alkynes with 1,3-dienes led to dihydroaromatic intermediates which were transformed into iodobenzene derivatives. For this transformation, the dihydroaromatic intermediates had to be oxidized and the trimethylsilyl-substituted arene had to undergo a silicon-iodine exchange reaction.
Synthesis, kinetic observations and characteristics of polyarylene ether sulphones prepared via a potassium carbonate DMAC process.
Viswanathan R, et al.
Polymer, 25(12), 1827-1836 (1984)

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