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94950

Supelco

4-Vinyl-1-cyclohexene

analytical standard

Sinonimo/i:

4-Ethenyl-1-cyclohexene, NSC 15760

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About This Item

Formula condensata:
C6H9CH=CH2
Numero CAS:
100-40-3
Peso molecolare:
108.18
Beilstein:
1901553
Numero CE:
202-848-9
Numero MDL:
MFCD00001576
Codice UNSPSC:
41116107
ID PubChem:
329770400
NACRES:
NA.24

Grado

analytical standard

Livello qualitativo

100

Densità del vapore

3.76 (vs air)

Tensione di vapore

10.2 mmHg ( 25 °C)

Saggio

≥99.5% (GC)

Temp. autoaccensione

517 °F

Durata

limited shelf life, expiry date on the label

tecniche

HPLC: suitable
gas chromatography (GC): suitable

Indice di rifrazione

n20/D 1.463 (lit.)
n20/D 1.464

P. ebollizione

126-127 °C (lit.)

Punto di fusione

−101 °C (lit.)

Densità

0.831 g/mL at 20 °C
0.831 g/mL at 20 °C
0.832 g/mL at 25 °C (lit.)

applicazioni

environmental
petroleum

Formato

neat

Temperatura di conservazione

2-8°C

Stringa SMILE

C=CC1CCC=CC1

InChI

1S/C8H12/c1-2-8-6-4-3-5-7-8/h2-4,8H,1,5-7H2
BBDKZWKEPDTENS-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

4-Vinyl-1-cyclohexene can be synthesized via cyclo-dimerization of butadiene in the presence of nitrosyl iron catalysts like [Fe(NO)2(CO)2] or [{FeCl(NO)2}2]/reductant.

Applicazioni

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Prodotti consigliati

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Avvertenze

Danger

Indicazioni di pericolo

H225,H304,H315,H351,H361,H412

Classi di pericolo

Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

60.8 °F - closed cup

Punto d’infiammabilità (°C)

16 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
BCCG5086
BCCG7880
BCBZ3843
BCBT2046

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Sigma-Aldrich

M35800

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2-Ethyl-1-hexanol analytical standard

Supelco

08607

2-Ethyl-1-hexanol

Methylenecyclohexane 98%

Sigma-Aldrich

111015

Methylenecyclohexane

Inorganic Reactions and Methods, Reactions Catalyzed by Inorganic Compounds (2009)
D A Keller et al.
Toxicology and applied pharmacology, 144(1), 36-44 (1997-05-01)
4-Vinylcyclohexene (4-VCH), the dimer of 1,3-butadiene, is an ovarian toxicant in mice due to the formation of a diepoxide metabolite, but the tissue-specific site of formation of the metabolites is unknown. Microsomal preparations from liver, lung, and ovaries obtained from
S M Borman et al.
Toxicology and applied pharmacology, 167(3), 191-198 (2000-09-14)
Extensive destruction of primordial follicles by exposure to ovarian toxicants can cause early menopause in women. Primordial follicle destruction is known to result from dosing of mice and rats with three polycyclic aromatic hydrocarbons (PAHs), contaminants commonly found in cigarette
S M Fontaine et al.
Drug metabolism and disposition: the biological fate of chemicals, 29(9), 1236-1242 (2001-08-15)
4-Vinyl-1-cyclohexene (VCH) is ovotoxic in B6C3F(1) mice but not in Fischer-344 rats, which can be partially attributed to greater formation of toxic epoxides from VCH in mice compared with rats. Since repeated exposure to VCH is necessary to cause ovotoxicity
Cinzia Chiappe et al.
Chemical research in toxicology, 16(1), 56-65 (2003-04-16)
The stereochemical course of the biotransformation of 1,2-monoepoxides of 4-vinylcyclohexene (2 and 3) by liver microsomes from control and induced rats and by purified P4502B1 and P4502E1 has been determined. The epoxidation of monoexpodies cis-4-vinylcyclohexene 1,2-epoxide (2) and trans-4-vinylcyclohexene 1,2-epoxide
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