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31690

Sigma-Aldrich

Dietiletere

≥99.8% (GC), puriss. p.a., ACS reagent, contains ~0.0005% 2, 6-di-tert-butyl-4-methylphenol as stabilizer

Sinonimo/i:

Etere, Etil etere

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About This Item

Formula condensata:
(CH3CH2)2O
Numero CAS:
Peso molecolare:
74.12
Beilstein:
1696894
Numero CE:
Numero MDL:
Codice UNSPSC:
12352112
ID PubChem:

product name

Dietiletere, puriss. p.a., ACS reagent, ≥99.8% (GC)

Grado

ACS reagent
puriss. p.a.

Livello qualitativo

Densità del vapore

2.6 (vs air)

Saggio

≥99.8% (GC)

Forma fisica

liquid

Temp. autoaccensione

320 °F

contiene

~0.0005% 2,6-di-tert-butyl-4-methylphenol as stabilizer

Limite di esplosione

36.5 %

Impurezze

≤0.00003% peroxides (as H2O2)
≤0.0002 meq/g Titr. acid
≤0.0005% free acid (as CH3COOH)
≤0.001% acetaldehyde (CH3CHO)
≤0.001% formaldehyde (HCHO)
≤0.1% water
<0.002% ketone (as CH3COCH3)

Residuo dopo evaporazione

≤0.001%

Indice di rifrazione

n20/D 1.3530 (lit.)
n20/D 1.353

P. eboll.

34.6 °C (lit.)

Punto di fusione

−116 °C (lit.)

Densità

0.706 g/mL at 25 °C (lit.)

Cationi in tracce

Al: ≤0.5 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

Stringa SMILE

CCOCC

InChI

1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3
RTZKZFJDLAIYFH-UHFFFAOYSA-N

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Descrizione generale

Diethyl ether (DEE) is widely employed as solvent for Grignard synthesis. Its efficacy as solvent for Formalin-ether (F-E) sedimentation technique has been studied. It has been reported as a hydroboration solvent. DEE is a promising compression-ignition fuel and its energy density is much higher than ethanol. It is also one of the components in a blend used in diesel fuel.

Applicazioni

Diethyl ether may be employed as solvent for the oxidation of secondary alcohols into ketones. It may be employed as solvent in the preparation of triblock copolymer of PCL-PEG-PCL, acrylated PCL-PEG-PCL and the pentablock copolymer PAE-PCL-PEG-PCL-PAE [PAE = poly(β-amino ester), PEG = poly(ethylene glycol), PCL = poly(ε-caprolactone)].

Altre note

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.
Sales restrictions may apply

Pittogrammi

FlameExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Flam. Liq. 1 - STOT SE 3

Organi bersaglio

Respiratory system

Rischi supp

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

-40.0 °F - closed cup

Punto d’infiammabilità (°C)

-40 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves


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Dai P Huynh et al.
Biomaterials, 29(16), 2527-2534 (2008-03-11)
The concept of this research is using poly(beta-amino ester) (PAE) as a duo-functional group for synthesis of the novel sensitive injectable hydrogel for controlled drug/protein delivery. Firstly, PAE made of 1,4-butanediol diacrylate and 4,4'-trimethylene dipiperidine is used as a pH-sensitive
Diethyl ether (DEE) as a renewable diesel fuel.
Bailey B, et al.
No. 972978. SAE technical paper (1997)
Eagleson M.
Concise Encyclopedia Chemistry, 471-471 (1994)
Oxidation of secondary alcohols in diethyl ether with aqueous chromic acid. Convenient procedure for the preparation of ketones in high epimeric purity.
Brown HC, et al.
The Journal of Organic Chemistry, 36(3), 387-390 (1971)
K H Young et al.
Journal of clinical microbiology, 10(6), 852-853 (1979-12-01)
Ethyl acetate appears to be a satisfactory subsitute solvent for diethyl ether in the Formalin-ether sedimentation technique. In comparative studies, concentration of organisms with ethyl acetate was equal to or greater than that with diethyl ether. No distortion or alteration

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