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M79204

Sigma-Aldrich

N-Methylpyrrolidine

97%

Sinonimo/i:

1-Methylpyrrolidine, N-Methylpyrrolidine, N-Methyltetrahydropyrrole

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About This Item

Formula empirica (notazione di Hill):
C5H11N
Numero CAS:
120-94-5
Peso molecolare:
85.15
Beilstein:
102445
Numero CE:
204-438-5
Numero MDL:
MFCD00003173
Codice UNSPSC:
12352100
ID PubChem:
24897203
NACRES:
NA.22

Livello qualitativo

200

Saggio

97%

Forma fisica

liquid

P. eboll.

80-81 °C (lit.)

Densità

0.819 g/mL at 25 °C (lit.)

Stringa SMILE

CN1CCCC1

InChI

1S/C5H11N/c1-6-4-2-3-5-6/h2-5H2,1H3
AVFZOVWCLRSYKC-UHFFFAOYSA-N

Categorie correlate

Applicazioni

N-Methylpyrrolidine can be used as a starting material to synthesize:
N-methyl pyrrolidine-zinc borohydride (ZBHNMP), a reducing agent for reduction of aldehydes, ketones, acid chlorides, and esters. ZBHNMP is also used in the reductive amination of aldehydes and ketones to their corresponding amines.
N-alkyl-N-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide ionic liquids.
N-methylpyrrolidine-2-one hydrotribromide applicable as a catalyst for aziridination of alkenes.

Avvertenze

Danger

Indicazioni di pericolo

H225,H301,H314,H332,H411

Classi di pericolo

Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Flam. Liq. 2 - Skin Corr. 1A

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

-0.4 °F - closed cup

Punto d’infiammabilità (°C)

-18 °C - closed cup

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
BCCH0060
BCCG9619
BCCG6715
BCCC5874
BCBW8625

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Sigma-Aldrich

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1-metil-2-pirrolidinone analytical standard

Supelco

78769

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Residual Solvent Class 2 - N-Methylpyrrolidone United States Pharmacopeia (USP) Reference Standard

USP

1601703

Residual Solvent Class 2 - N-Methylpyrrolidone

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Supelco

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Reductive amination of aldehydes and ketones to their corresponding amines with N-methylpyrrolidine zinc borohydride
Alinezhad H, et al.
Tetrahedron Letters, 50(6), 659-661 (2009)
N-methylpyrrolidine-2-one hydrotribromide: An efficient and new catalyst for the aziridination of alkenes using Chloramine-T under solvent free conditions
Jain SL, et al.
J. Mol. Catal. A: Chem., 256(1-2), 16-20 (2006)
Effect of the alkyl group on the synthesis and the electrochemical properties of N-alkyl-N-methyl-pyrrolidinium bis (trifluoromethanesulfonyl) imide ionic liquids
Appetecchi GB, et al.
Electrochimica Acta, 54(4), 1325-1332 (2009)
N-Methylpyrrolidine-zinc borohydride: As a new stable and efficient reducing agent in organic synthesis
Tajbakhsh M, et al.
Synthetic Communications, 33(2), 229-236 (2003)
Chafik Ghayor et al.
The Journal of biological chemistry, 286(27), 24458-24466 (2011-05-27)
Regulation of RANKL (receptor activator of nuclear factor κB ligand)-induced osteoclast differentiation is of current interest in the development of antiresorptive agents. Osteoclasts are multinucleated cells that play a crucial role in bone resorption. In this study, we investigated the
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