930008

RuCl(p-cymene)[(R,R)-Ts-DPEN]

• Sinonimo/i: [N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
• Formula empirica (notazione di Hill): C₃₁H₃₅ClN₂O₂RuS
• Numero CAS: 192139-92-7
• Peso molecolare: 636.21
• Numero MDL: MFCD10567385
• Codice UNSPSC: 12352116
• NACRES: NA.21

Proprietà

• Forma fisica: powder or crystals
• Livello qualitativo: 100
• Punto di fusione: 215 °C
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
• InChI: 1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1; AZFNGPAYDKGCRB-AGEKDOICSA-M

Descrizione

Applicazioni

Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:

• Quinolines
• N-Alkyl ketimines
• Antitumor and antiproliferative derivatives of natural products isolated from bacteria
• Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation

Catalyst with improved performance modified via microenvironment engineering of nanocages

RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium used for asymmetric hydrogenation reactions.

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable