923443

PhMPhos

• Sinonimo/i: 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene
• Formula empirica (notazione di Hill): C₄₂H₄₈FeP₂
• Peso molecolare: 670.62
• Codice UNSPSC: 12352200
• NACRES: NA.21

Proprietà

• Forma fisica: powder
• Livello qualitativo: 100
• Impiego in reazioni chimiche: reagent type: catalyst; reaction type: Cross Couplings; reagent type: ligand
• Gruppo funzionale: phosphine

Descrizione

Applicazioni

PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Altre note

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable