901409
[Ir(dF(Me)ppy)2(dtbbpy)]PF6
Sinonimo/i:
Iridium(III) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate
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About This Item
Formula empirica (notazione di Hill):
C42H40F10IrN4P
Numero CAS:
Peso molecolare:
1013.97
Numero MDL:
Codice UNSPSC:
12161600
NACRES:
NA.22
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Stato
solid
Livello qualitativo
Impiego in reazioni chimiche
core: iridium
reaction type: Photocatalysis
reagent type: catalyst
Attivazione fotocatalizzatore
450 nm
InChI
XAJPUJWOMJJPNU-UHFFFAOYSA-N
Categorie correlate
Applicazioni
[Ir(dF(Me)ppy)2(dtbbpy)]PF6 is a photocatalyst readily facilitates hydroamination of olefins as well as the decarboxylative arylation and vinylation of carboxylic acids via metallaphotoredox catalysis.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Altre note
Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines
Merging photoredox and nickel catalysis: Decarboxylative cross-coupling of carboxylic acids with vinyl halides
Enhanced luminescent iridium(III) complexes bearing aryltriazole cyclometallated ligands
Site-Selective and Stereoselective C-H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis
Merging photoredox and nickel catalysis: Decarboxylative cross-coupling of carboxylic acids with vinyl halides
Enhanced luminescent iridium(III) complexes bearing aryltriazole cyclometallated ligands
Site-Selective and Stereoselective C-H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis
Prodotti correlati
N° Catalogo
Descrizione
Determinazione del prezzo
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
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European Journal of Inorganic Chemistry, 2013(30), 5329-5343 (2013)
Andrew J Musacchio et al.
Science (New York, N.Y.), 355(6326), 727-730 (2017-02-18)
The intermolecular hydroamination of unactivated alkenes with simple dialkyl amines remains an unsolved problem in organic synthesis. We report a catalytic protocol for efficient additions of cyclic and acyclic secondary alkyl amines to a wide range of alkyl olefins with
Correlating electronic structures to electrochemiluminescence of cationic Ir complexes.
Swanick KN, et al.
Royal Society of Chemistry Advances, 43, 19961-19964 (2013)
Adam Noble et al.
Journal of the American Chemical Society, 137(2), 624-627 (2014-12-19)
Decarboxylative cross-coupling of alkyl carboxylic acids with vinyl halides has been accomplished through the synergistic merger of photoredox and nickel catalysis. This new methodology has been successfully applied to a variety of α-oxy and α-amino acids, as well as simple
Sébastien Ladouceur et al.
Inorganic chemistry, 50(22), 11514-11526 (2011-10-04)
Herein we report the synthesis of 4-aryl-1-benzyl-1H-1,2,3-triazoles (atl), made via "Click chemistry" and their incorporation as cyclometallating ligands into new heteroleptic iridium(III) complexes containing diimine (N(^)N) ancillary ligands 2,2'-bipyridine (bpy) and 4,4'-di-tert-butyl-2,2'-bipyridine (dtBubpy). Depending on decoration, these complexes emit from
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 901409-100MG | 4061835503476 |
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