693383
Mo-Phos
Sinonimo/i:
Di-tert-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine
About This Item
Prodotti consigliati
![[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)](/deepweb/assets/sigmaaldrich/product/structures/130/734/8846aa26-1858-458a-998d-8c306c13bf0f/640/8846aa26-1858-458a-998d-8c306c13bf0f.png)
Stato
crystals
Impiego in reazioni chimiche
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
Punto di fusione
87-91 °C
Gruppo funzionale
phosphine
Stringa SMILE
CC(C)(C)P(C(C)(C)C)C1(C)CC1(c2ccccc2)c3ccccc3
InChI
1S/C24H33P/c1-21(2,3)25(22(4,5)6)23(7)18-24(23,19-14-10-8-11-15-19)20-16-12-9-13-17-20/h8-17H,18H2,1-7H3
QMLPJDVGNRHGJQ-UHFFFAOYSA-N
Applicazioni
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
Note legali
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
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Articoli
TPGS-750-M, a second generation surfactant, is useful for room temperature, palladium and ruthenium-catalyzed reactions in water. Reactions include the Heck reaction, Suzuki-Miyaura reaction, Sonogashira reaction, Buchwald-Hartwig amination reaction, Negishi reaction, and olefin metathesis.
Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago
Protocolli
Buchwald-Hartwig Amination Reaction in Water at Room Temperature using TPGS-750-M
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