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441791

Sigma-Aldrich

Tris(2,4-di-tert-butylphenyl) phosphite

Sinonimo/i:

2,4-Bis(1,1-dimethylethyl)phenol phosphite (3:1), Tri(2,4-di-tert -butylphenyl) phosphite, Tri(2,4-di-t -butylphenyl) phosphite

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About This Item

Formula condensata:
[[(CH3)3C]2C6H3O]3P
Numero CAS:
31570-04-4
Peso molecolare:
646.92
Numero CE:
250-709-6
Numero MDL:
MFCD00072706
Codice UNSPSC:
12162002
ID PubChem:
24867703
NACRES:
NA.23

Livello qualitativo

200

Punto di fusione

181-184 °C (lit.)

Stringa SMILE

CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C

InChI

1S/C42H63O3P/c1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18/h19-27H,1-18H3
JKIJEFPNVSHHEI-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Tris(2,4-di-tert-butylphenyl) phosphite is a triaryl based phosphite that can be used in catalysis and metallation. Its characteristic to undergo metallation reaction and provide a cost effective synthetic processes allows it to be useful in biaryl coupling reactions.

Applicazioni

It may be used as a chain extender and a processing stabilizer that facilitate the production of stable polymeric materials, which include polylactic acid (PLA), polyolefins, etc.

Codice della classe di stoccaggio

13 - Non Combustible Solids

Classe di pericolosità dell'acqua (WGK)

nwg

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)

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Certificati d'analisi (COA)

Lot/Batch Number
MKCP9084
MKCM9348
MKCH4066
MKCF6542
MKCB9205

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Supelco

PHR2174

Plastic Additive 4

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P2155009

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Plastic additive 10

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3,9-Bis(octadecyloxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane

Sigma-Aldrich

441775

3,9-Bis(octadecyloxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane

Study of the high temperature reactions of a hindered aryl phosphite (Hostanox PAR 24) used as a processing stabiliser in polyolefins.
Kriston I, et al.
Polymer Degradation and Stability, 95(9), 1883-1893 (2010)
Orthopalladated triaryl phosphite complexes as highly active catalysts in biaryl coupling reactions.
Albisson DA, et al.
Chemical Communications (Cambridge, England), 19, 2095-2096 (1998)
Orthopalladated triarylphosphite complexes as highly efficient catalysts in the Heck reaction.
Albisson DA
Tetrahedron Letters, 39(52), 9793-9796 (1998)
Taoufiq Mouhib et al.
Journal of the American Society for Mass Spectrometry, 21(12), 2005-2010 (2010-09-25)
The enhancement of the static secondary ion mass spectrometry (SIMS) signals resulting from the injection, closely to the sample surface, of H(2)O vapor at relatively high-pressure, was investigated for a set of organic materials. While the ion signals are generally
Yasuo Tanaka et al.
Shokuhin eiseigaku zasshi. Journal of the Food Hygienic Society of Japan, 44(4), 181-185 (2003-11-11)
Two peaks, A and B, detected in chromatograms of commercial frozen vegetable extracts during analysis of organophosphorus pesticide residues by GC-FPD, were identified as tris(2,4-ditert-butylphenyl)phosphite (Irgafos 168) and Irgafos 168 oxide, respectively, from their mass spectra. Irgafos 168 is used
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