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Sigma-Aldrich

2,2,2-Trifluoroethanethiol

95%

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About This Item

Formula condensata:
CF3CH2SH
Numero CAS:
Peso molecolare:
116.11
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

Tensione di vapore

7.85 psi ( 20 °C)

Saggio

95%

Stato

liquid

Indice di rifrazione

n20/D 1.352 (lit.)

P. ebollizione

34-35 °C (lit.)

Densità

1.305 g/mL at 25 °C (lit.)

Gruppo funzionale

fluoro
thiol

Stringa SMILE

FC(F)(F)CS

InChI

1S/C2H3F3S/c3-2(4,5)1-6/h6H,1H2
RYRLLAOLJVDVNN-UHFFFAOYSA-N

Descrizione generale

2,2,2-Trifluoroethanethiol is a fluorinated thiol. The microwave spectrum of 2,2,2-trifluoroethanethiol, and its deuterated species, CF3CH2SD has been studied. The gas phase acidity and basicity of 2,2,2-trifluoroethanethiol (TFET) has been investigated by Fourier transform ion cyclotron resonance spectroscopy. Reaction of 2,2,2-trifluoroethanethiol on Mo(110) surface was studied using temperature-programmed section, Auger electron and infrared spectroscopies.
2,2,2-Trifluoroethanethiol is basic in nature and forms charge transfer complexes with molecular iodine.

Applicazioni


  • Advancements in Peptide Synthesis: A novel synthesis of β-thiol phenylalanine showcases the use of 2,2,2-Trifluoroethanethiol in facilitating one-pot ligation-desulfurization chemistry. This technique is pivotal for developing new peptide-based pharmaceuticals, enhancing both the efficiency and versatility of peptide synthesis (Malins et al., 2015).

Accessorio

N° Catalogo
Descrizione
Determinazione del prezzo

Pittogrammi

FlameExclamation mark

Avvertenze

Danger

Classi di pericolo

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

-11.2 °F - closed cup

Punto d’infiammabilità (°C)

-24 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves


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I clienti hanno visto anche

Intrinsic (gas-phase) basicities and stability of charge-transfer complexes in solution.
Bouab W, et al.
Journal of Physical Organic Chemistry, 10(5), 343-346 (1997)
Effect of Fluorination on Thiol Reactivity: Reaction of 2, 2, 2-Trifluoroethanethiol on Mo (110).
Napier ME and Friend CM.
The Journal of Physical Chemistry, 99(21), 8750-8757 (1995)
Intrinsic acidity and basicity of 2, 2, 2-trifluoroethanethiol. The first experimental and theoretical study.
Molina MT, et al.
The Journal of Organic Chemistry, 61(16), 5485-5491 (1996)
Dong Min Sim et al.
ACS nano, 9(12), 12115-12123 (2015-10-28)
MoS2 is considered a promising two-dimensional active channel material for future nanoelectronics. However, the development of a facile, reliable, and controllable doping methodology is still critical for extending the applicability of MoS2. Here, we report surface charge transfer doping via
Harald Møllendal
The journal of physical chemistry. A, 112(32), 7481-7487 (2008-07-22)
The microwave spectrum of 2,2,2-trifluoroethanethiol, CF3CH2SH, and of one deuterated species, CF3CH2SD, has been investigated in the 7-80 GHz spectral interval. The microwave spectra of the ground and three vibrationally excited states belonging to three different normal modes of one

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