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341169

Sigma-Aldrich

Zinc phthalocyanine

Dye content 97 %

Sinonimo/i:

Phthalocyanine zinc salt

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About This Item

Formula empirica (notazione di Hill):
C32H16N8Zn
Numero CAS:
14320-04-8
Peso molecolare:
577.91
Beilstein:
4121852
Numero CE:
238-262-5
Numero MDL:
MFCD00041955
Codice UNSPSC:
12352103
ID PubChem:
24860701
NACRES:
NA.23

Composizione

Dye content, 97%

Impiego in reazioni chimiche

reagent type: catalyst
core: zinc

λmax

701 nm

Energia dell’orbitale

HOMO 5.17 eV (CV)
LUMO 3.78 eV (CV)

Prestazioni di un dispositivo OPV

ITO/ZnPc:P60 (1:1)/Bphen/Ag

  • Short-circuit current density (Jsc): 11.7 mA/cm2
  • Open-circuit voltage (Voc): 0.54 V
  • Fill Factor (FF): 0.62
  • Power Conversion Efficiency (PCE): 3.9 %

Stringa SMILE

[Zn]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10

InChI

1S/C32H16N8.Zn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2
PODBBOVVOGJETB-UHFFFAOYSA-N

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Descrizione generale

Zinc (II) phthalocyanine (ZnPc) complexes show photosensitizing properties. Phthalocyanines show significant Π−Π interactions and easy formation of H aggregates.

Applicazioni

Zinc phthalocyanine finds general applications in industry (catalysts, photoconductors etc) and biomedical (photodynamic therapy, PDT). ZnPc may be used to photooxidise cyclohexane. A study reports functionalization of polymer membrane with ZnPc.

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)

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Certificati d'analisi (COA)

Lot/Batch Number
MKCN2418
MKCH0531
MKCB8578
MKBV2160V
MKBQ2164V

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Copper(II) phthalocyanine β-form, Dye content 90 %

Sigma-Aldrich

252980

Copper(II) phthalocyanine

Zinc 1,4,8,11,15,18,22,25-octabutoxy-29H,31H-phthalocyanine

Sigma-Aldrich

383813

Zinc 1,4,8,11,15,18,22,25-octabutoxy-29H,31H-phthalocyanine

Copper(II) phthalocyanine triple-sublimed grade, >99.95% trace metals basis

Sigma-Aldrich

702854

Copper(II) phthalocyanine

Ye-Liang Wang et al.
Chimia, 66(1-2), 31-37 (2012-05-02)
We report on high-resolution STM measurements with modified probe tips. First, both the rest atoms and adatoms of a Si(111)-7×7 surface are observed simultaneously. The visibility of rest atoms is dependent upon the sample bias voltage (less than -0.7 V)
Anamika Ray et al.
The journal of physical chemistry. B, 116(39), 11979-11998 (2012-08-23)
The present article reports photophysical studies on supramolecular interaction of a zinc phthalocyanine derivative, namely, zinc-2,9,16,23-tetra-tert-butyl phthalocyanine (1) with C(60) and C(70) in solvents having varying polarity, i.e., toluene and 1,2-dichlorobenzene (DCB). The interesting feature of the present work is
Effect of blend layer morphology on performance of ZnPc:C60-based photovoltaic cells
Zeng, W.; et al.
Applied Physics Letters, 97, 133304-133304 (2010)
Thandekile P Mthethwa et al.
Dalton transactions (Cambridge, England : 2003), 42(14), 4922-4930 (2013-02-07)
A novel thiol functionalized zinc phthalocyanine complex (ZnPcSH) is reported in this work. This complex was conjugated to gold nanoparticles. The photophysical and photochemical properties of the complex and the conjugate were investigated. Upon conjugation a blue shift was observed
Sean Marrache et al.
Integrative biology : quantitative biosciences from nano to macro, 5(1), 215-223 (2012-07-27)
A therapeutic technology that combines the phototoxic and immune-stimulating ability of photodynamic therapy (PDT) with the widespread effectiveness of the immune system can be very promising to treat metastatic breast cancer. We speculated that the knowledge of molecular mechanisms of
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