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317632

Sigma-Aldrich

(Methylcyclopentadienyl)manganese(I) tricarbonyl

Sinonimo/i:

(Methylcyclopentadienyl)tricarbonylmanganese, MCMT, Tricarbonyl(2-methylcyclopentadienyl)manganese, Ethyl MMT, MMT, NSC 22316

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About This Item

Formula condensata:
C5H4CH3Mn(CO)3
Numero CAS:
12108-13-3
Peso molecolare:
218.09
Numero CE:
235-166-5
Numero MDL:
MFCD00001426
Codice UNSPSC:
12161600
ID PubChem:
24859093
NACRES:
NA.22

Densità del vapore

>1 (vs air)

Livello qualitativo

100

Tensione di vapore

0.05 mmHg ( 20 °C)

Forma fisica

liquid

Impiego in reazioni chimiche

core: manganese
reagent type: catalyst

Indice di rifrazione

n20/D 1.584 (lit.)

P. eboll.

232-233 °C (lit.)

Punto di fusione

−1 °C (lit.)

Densità

1.38 g/mL at 25 °C (lit.)

Stringa SMILE

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].C[C]1[CH][CH][CH][CH]1

InChI

1S/C6H7.3CO.Mn/c1-6-4-2-3-5-6;3*1-2;/h2-5H,1H3;;;;
LYHJNAIHGFWRKM-UHFFFAOYSA-N

Categorie correlate

Descrizione generale

Methylcyclopentadienyl manganese tricarbonyl (MMT) is commonly used as an antiknock agent in gasoline. It is also used as an additive in unleaded gasoline.

Applicazioni

Methylcyclopentadienyl manganese tricarbonyl can be used for doping of ZnSe nanocrystals.
It can also be used as a reactant for:
  • Aldol addition reactions.
  • Preparation of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units.
  • Molecular fragmentation using shaped femtosecond laser pulses.
  • Preparation of MnAs thin films grown on GaAs(001) by metalorganic vapour phase epitaxy (MOVPE).

Avvertenze

Danger

Indicazioni di pericolo

H301,H310 + H330,H315,H372,H410

Classi di pericolo

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Irrit. 2 - STOT RE 1 Inhalation

Organi bersaglio

Lungs

Codice della classe di stoccaggio

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

204.8 °F - closed cup

Punto d’infiammabilità (°C)

96 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
MKCP0166
MKBL1371V
MKBH5032V
MKBG2700V
MKBH0068V

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Afsaneh Nouri et al.
International journal of biological macromolecules, 109, 1219-1231 (2017-11-25)
Montmorillonite -copper oxide (MMT-CuO) nanocomposites were prepared by a facile and eco-friendly method and introduced into chitosan (Cs) matrix to enhance its optical, mechanical and antibacterial properties. The synthesized composites were characterized using diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD)
Properties of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units
Landman, M.; et al.
Inorgorganica Chimica Acta, 363, 705-705 (2010)
Einat Peles et al.
The world journal of biological psychiatry : the official journal of the World Federation of Societies of Biological Psychiatry, 15(8), 620-628 (2014-03-29)
Methadone maintenance treatment (MMT) patients may achieve up to a 2-week privilege of methadone take-home doses (THD), which is associated with considerable responsibility. MMT patients are characterized as having poor sleep quality and low cognitive states. We studied sleep indices
Nacéra Boudia et al.
The Science of the total environment, 366(1), 143-147 (2005-11-22)
Methylcyclopentadienyl manganese tricarbonyl (MMT) is an organic derivative of manganese (Mn), used since 1976 in Canadian gasoline as an octane enhancer. Its combustion leads to the emission of Mn particles. Several studies carried out by our research group have established
Vadim V Lozovoy et al.
The journal of physical chemistry. A, 112(17), 3789-3812 (2008-04-25)
The possibility that chemical reactions may be controlled by tailored femtosecond laser pulses has inspired recent studies that take advantage of their short pulse duration, comparable to intramolecular dynamics, and high peak intensity to fragment and ionize molecules. In this
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