Passa al contenuto
Merck
Tutte le immagini(2)

Documenti fondamentali

Visualizza tutta la documentazione

238325

Sigma-Aldrich

Allyl iodide

98%

Sinonimo/i:

3-Iodo-1-propene

Autenticatiper visualizzare i prezzi riservati alla tua organizzazione & contrattuali
Tutte le immagini(2)

About This Item

Formula condensata:
CH2=CHCH2I
Numero CAS:
556-56-9
Peso molecolare:
167.98
Beilstein:
1697594
Numero CE:
209-130-4
Numero MDL:
MFCD00001094
Codice UNSPSC:
12352100
ID PubChem:
24854295
NACRES:
NA.22

Livello qualitativo

100

Saggio

98%

Stato

liquid

contiene

copper as stabilizer

Indice di rifrazione

n20/D 1.554 (lit.)

P. ebollizione

102-103 °C (lit.)

Solubilità

alcohol: miscible(lit.)
chloroform: miscible(lit.)
diethyl ether: miscible(lit.)
water: insoluble (practically)(lit.)

Densità

1.837 g/mL at 25 °C (lit.)

Gruppo funzionale

alkyl halide
iodo

Temperatura di conservazione

2-8°C

Stringa SMILE

ICC=C

InChI

1S/C3H5I/c1-2-3-4/h2H,1,3H2
HFEHLDPGIKPNKL-UHFFFAOYSA-N

Cerchi prodotti simili? Visita Guida al confronto tra prodotti

Descrizione generale

The interaction of allyl iodide with MoO3, Bi2O3 and molybdates of Bi, Co and Mg has been studied in the temperature range of 270-480°C.

Applicazioni

Allyl iodide has been employed as:
  • precursor for generation of allyl radicals to study their recombination in a single pulse shock tube with gas chromatographic measurements
  • reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes

Avvertenze

Danger

Indicazioni di pericolo

H225,H300,H314

Classi di pericolo

Acute Tox. 2 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

60.8 °F - closed cup

Punto d’infiammabilità (°C)

16 °C - closed cup

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Scegli una delle versioni più recenti:

Certificati d'analisi (COA)

Lot/Batch Number
MKCQ7060
MKCN9231
MKCM1182
MKCH7582
MKCH1622

Non trovi la versione di tuo interesse?

Se hai bisogno di una versione specifica, puoi cercare il certificato tramite il numero di lotto.

Cerca un COA

Possiedi già questo prodotto?

I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.

Visita l’Archivio dei documenti

I clienti hanno visto anche

Slide 1 of 5

1 of 5

1-Naphthyl phosphate 99%

Sigma-Aldrich

N5602

1-Naphthyl phosphate

1-Iodopropane 99%

Sigma-Aldrich

171883

1-Iodopropane

Crotyl bromide technical grade, 85% (mixture of cis & trans)

Sigma-Aldrich

C86405

Crotyl bromide

Perfluorobutyryl chloride 98%

Sigma-Aldrich

257923

Perfluorobutyryl chloride

Allyl glycidyl ether ≥99%

Sigma-Aldrich

A32608

Allyl glycidyl ether

Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons.
Grzybowska B, et al.
J. Catal., 49(2), 150-163 (1977)
Aleksandr Fridlyand et al.
The journal of physical chemistry. A, 117(23), 4762-4776 (2013-05-18)
The recombination and disproportionation of allyl radicals has been studied in a single pulse shock tube with gas chromatographic measurements at 1-10 bar, 650-1300 K, and 1.4-2 ms reaction times. 1,5-Hexadiene and allyl iodide were used as precursors. Simulation of
Tsunehisa Hirashita et al.
Organic & biomolecular chemistry, 5(13), 2154-2158 (2007-06-22)
The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded with a cis-addition mode in the presence of other organometallics (e.g. Grignard reagent, cuprate, Et(2)Zn and Et(3)Al), giving the corresponding cis-diallylcyclopropanes in high yields.
Xin Ma et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(25), 6355-6361 (2019-02-28)
Unexpectedly, the 5-dehydroquinoline radical cation was formed in the gas phase from the 5-iodo-8-nitroquinolinium cation upon ion-trap collision-activated dissociation. This reaction involves the cleavage of a nitro group to generate an intermediate monoradical, namely, the 8-dehydro-5-iodoquinolinium cation, followed by rearrangement
Michael Lesslie et al.
European journal of mass spectrometry (Chichester, England), 21(3), 589-597 (2015-08-27)
Radical migration, both intramolecular and intermolecular, from the tyrosine phenoxyl radical Tyr(O(∙)) to the cysteine radical Cys(S(∙)) in model peptide systems was observed in the gas phase. Ion-molecule reactions (IMRs) between the radical cation of homotyrosine and propyl thiol resulted

Il team dei nostri ricercatori vanta grande esperienza in tutte le aree della ricerca quali Life Science, scienza dei materiali, sintesi chimica, cromatografia, discipline analitiche, ecc..

Contatta l'Assistenza Tecnica.