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Key Documents

Altri documenti

193984

Sigma-Aldrich

1-Methylindole

≥97%

Sinonimo/i:

NSC 212534

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About This Item

Formula empirica (notazione di Hill):
C9H9N
Numero CAS:
603-76-9
Peso molecolare:
131.17
Beilstein:
111026
Numero CE:
210-057-5
Numero MDL:
MFCD00005800
Codice UNSPSC:
12352100
ID PubChem:
24851625
NACRES:
NA.22

Saggio

≥97%

Forma fisica

liquid

Indice di rifrazione

n20/D 1.606 (lit.)

P. eboll.

133 °C/26 mmHg (lit.)

Densità

1.051 g/mL at 20 °C (lit.)

Stringa SMILE

Cn1ccc2ccccc12

InChI

1S/C9H9N/c1-10-7-6-8-4-2-3-5-9(8)10/h2-7H,1H3
BLRHMMGNCXNXJL-UHFFFAOYSA-N

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Descrizione generale

1-Methylindole undergoes Au(III)/TPPMS-catalyzed benzylation reaction with benzhydryl and benzylic alcohols.

Applicazioni

1-Methylindole was used in the determination of association constant for the electron-donor-acceptor complexes of 1-methylindole with 1-(2,4,6-trinitrophenyl) propan-2-one.
Reactant for preparation of:
  • Pharmaceutically active 2-oxo-1-pyrrolidine analogues
  • Non-receptor tyrosine kinase (Src kinase) inhibitors
  • PET agents for imaging of protein kinase C (PKC)
  • Ynediones as highly reactive Michael systems
  • Anticancer agents
  • Polycyclic derivatives of indoles
  • PET agents for imaging of glycogen synthase kinase-3 (GSK-3)
  • Anti-prion disease agents
  • Bisindole derivatives with antihyperlipidemic activity
  • PET cancer imaging agents

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

235.4 °F - closed cup

Punto d’infiammabilità (°C)

113 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Certificati d'analisi (COA)

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Sigma-Aldrich

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Sigma-Aldrich

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Sigma-Aldrich

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Hidemasa Hikawa et al.
The Journal of organic chemistry, 78(23), 12128-12135 (2013-11-22)
A novel and efficient method for the Au(III)/TPPMS-catalyzed direct substitution reaction of benzhydryl and benzylic alcohols with indoles in water is developed. Au(III)/TPPMS is an effective catalyst for the benzylation of the strong π nucleophile 1-methylindole, while common Brønsted or
Martin G Banwell et al.
Organic letters, 8(21), 4959-4961 (2006-10-06)
[reaction: see text] Reaction of N-methylindole (4) with 6,6-dibromobicyclo[3.1.0]hexane (5) in the presence of silver tetrafluoroborate affords conjugate 7 in 67% yield. This product can be readily elaborated to compounds 12b and 13b which embody the polycyclic frameworks associated with
Hongmei Liu et al.
Malaria journal, 17(1), 348-348 (2018-10-07)
Anopheles sinensis is an important vector for the spread of malaria in China. Olfactory-related behaviours, particularly oviposition site seeking, offer opportunities for disrupting the disease-transmission process. This is the first report of the identification and characterization of AsinOrco and AsinOR10
Association constants for the electron-donor-acceptor complexes of indole and 1-methylindole with 1-(2, 4, 6-trinitrophenyl) propan-2-one from nuclear magnetic resonance shift measurements. An anomalous scatchard plot.
Chudek JA, et al.
J. Chem. Soc., Faraday, 84(4), 1145-1152 (1988)
Nicholas R Deprez et al.
Journal of the American Chemical Society, 128(15), 4972-4973 (2006-04-13)
This communication describes the rational development of a PdII-catalyzed method for the direct 2-arylation of indoles using [Ar-IIII-Ar]BF4. These reactions proceed under remarkably mild conditions (often at room temperature and in the presence of ambient air and moisture), and these
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