180211

Borane tert-butylamine complex

powder, 97%

• Sinonimo/i: tert-Butylamine borane, NSC 114045, Trihydro(2-methyl-2-propanamine) boron
• Formula condensata: (CH₃)₃CNH₂ · BH₃
• Numero CAS: 7337-45-3
• Peso molecolare: 86.97
• Numero CE: 230-851-5
• Numero MDL: MFCD00075635
• Codice UNSPSC: 12352116
• ID PubChem: 24850855
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Saggio: 97%
• Forma fisica: powder
• Impiego in reazioni chimiche: reagent type: reductant
• Punto di fusione: 98-100 °C (dec.) (lit.)
• Stringa SMILE: B.CC(C)(C)N
• InChI: 1S/C4H11N.BH3/c1-4(2,3)5;/h5H2,1-3H3;1H3; GKFJEDWZQZKYHV-UHFFFAOYSA-N

Descrizione

Descrizione generale

Borane tert-butylamine complex is a mild reducing agent. It participates in the selective reduction of aldehydes and ketones to corresponding alcohol. It takes part as a reducing agent in the synthesis of monodisperse palladium nanoparticles (Pd NPs), monodisperse gold (Au) nanoparticles and carbon-supported Pd electrocatalysts.

Applicazioni

Borane tert-butylamine (BTB) complex may be used as strong co-reducing agent in the following syntheses:

• copper (I) oxide nanoparticles
• diphosphine-protected gold nanocluster
• 4-acetoxycinnamyl alcohols

Reactant involved in:

• Non-destructive analyses and conservation treatments of Indian drawings
• Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes
• The formation of σ-borane complexes
• Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins
• Photochemical hydroboration and oxidation of single-walled carbon nanotubes

Informazioni sulla sicurezza

• Pittogrammi: GHS06,GHS09
• Avvertenze: Danger
• Indicazioni di pericolo: H301 + H311,H315,H319,H411
• Consigli di prudenza: P264 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338
• Classi di pericolo: Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2
• Codice della classe di stoccaggio: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges