15450
N,N′-Dimethylurea
(sym.), ≥99% (from N)
Sinonimo/i:
DMU, 1,3-Dimethylurea
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About This Item
Prodotti consigliati
Saggio
≥99% (from N)
Forma fisica
solid
Impiego in reazioni chimiche
reagent type: ligand
reaction type: C-H Activation
P. eboll.
268-270 °C (lit.)
Punto di fusione
101-104 °C (lit.)
103-107 °C
Stringa SMILE
CNC(=O)NC
InChI
1S/C3H8N2O/c1-4-3(6)5-2/h1-2H3,(H2,4,5,6)
MGJKQDOBUOMPEZ-UHFFFAOYSA-N
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Categorie correlate
Applicazioni
N,N′-Dimethylurea can be used:
- As a starting material to synthesize N,N′-dimethyl-6-amino uracil.
- In combination with β-cyclodextrin derivatives, to form low melting mixtures (LMMs), which can be used as solvents for hydroformylation and Tsuji-Trost reactions.
- To synthesize N,N′-disubstituted-4-aryl-3,4-dihydropyrimidinones via Biginelli condensation under solvent-free conditions.
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 1
Punto d’infiammabilità (°F)
314.6 °F - closed cup
Punto d’infiammabilità (°C)
157 °C - closed cup
Dispositivi di protezione individuale
Eyeshields, Gloves, type N95 (US)
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The binding behaviors of the 27-membered macrocyclic triurea 1 towards the five anions, F(-), Cl(-), Br(-), I(-) and NO(3)(-), through multiple hydrogen-bonding interactions, were investigated at the B3LYP/6-311++G(d,p)//B3LYP/6-31(1)++G(d,p) (6-31(1)++G(d,p) is a hybrid basis set; for more details see computational methods)
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