720526

Palladium(π-cinnamyl)chlorid-Dimer

97%

• Synonym(e): Bis-[cinnamyl-palladium(II)-chlorid], Palladium-(1-phenylallyl)-chlorid Dimer, [(Cinnamyl)PdCl]₂, [Pd(1-phenylallyl)Cl]₂
• Empirische Formel (Hill-System): C₁₈H₁₈Cl₂Pd₂
• CAS-Nummer: 12131-44-1
• Molekulargewicht: 518.08
• MDL-Nummer: MFCD16621470
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329763720
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 97%
• Form: solid
• Eignung der Reaktion: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp (Schmelzpunkt): 218-220 °C
• Lagertemp.: 2-8°C
• SMILES String: Cl[Pd].Cl[Pd].[CH2][CH][CH]c1ccccc1.[CH2][CH][CH]c2ccccc2
• InChI: 1S/2C9H9.2ClH.2Pd/c2*1-2-6-9-7-4-3-5-8-9;;;;/h2*2-8H,1H2;2*1H;;/q;;;;2*+1/p-2
• InChIKey: SHWAPUDBEQXXLQ-UHFFFAOYSA-L

Beschreibung

Anwendung

Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:

• Ammonia cross-coupling reactions to synthesize arylamines.
• Conversion of aryl triflates to fluorides.

It can also be used as a source of palladium in the asymmetric α-arylation of amides.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable