555142

1-Diphenylphosphin-1′-(di-tert-butylphosphin)ferrocen

• Empirische Formel (Hill-System): C₃₀H₃₆FeP₂
• CAS-Nummer: 95408-38-1
• Molekulargewicht: 514.40
• MDL-Nummer: MFCD03701526
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24879174
• NACRES: NA.22

Eigenschaften

• Form: solid
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Coupling Reactions
• mp (Schmelzpunkt): 75-79 °C (lit.)
• Funktionelle Gruppe: phosphine
• SMILES String: [Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.[CH]2[CH][CH][C]([CH]2)P(c3ccccc3)c4ccccc4
• InChI: 1S/C17H14P.C13H22P.Fe/c1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h1-14H;7-10H,1-6H3;
• InChIKey: GQIMIFFIUZZVMJ-UHFFFAOYSA-N

Beschreibung

Anwendung

• Catalyst in microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides
• Ligand for catalytic isomerization of methylbutenenitrile via nickel systems
• Ligand for ruthenium alkylidene complexes for catalysis of metathesis reactions and catalytic norbornene polymerization

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)