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Sigma-Aldrich

(Methylcyclopentadienyl)mangan(I)-tricarbonyl

Synonym(e):

MMT

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About This Item

Lineare Formel:
C5H4CH3Mn(CO)3
CAS-Nummer:
12108-13-3
Molekulargewicht:
218.09
EG-Nummer:
235-166-5
MDL-Nummer:
MFCD00001426
UNSPSC-Code:
12352300
PubChem Substanz-ID:
24859093
NACRES:
NA.22

Dampfdichte

>1 (vs air)

Qualitätsniveau

100

Dampfdruck

0.05 mmHg ( 20 °C)

Form

liquid

Eignung der Reaktion

core: manganese
reagent type: catalyst

Brechungsindex

n20/D 1.584 (lit.)

bp

232-233 °C (lit.)

mp (Schmelzpunkt)

−1 °C (lit.)

Dichte

1.38 g/mL at 25 °C (lit.)

SMILES String

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].C[C]1[CH][CH][CH][CH]1

InChI

1S/C6H7.3CO.Mn/c1-6-4-2-3-5-6;3*1-2;/h2-5H,1H3;;;;

InChIKey

LYHJNAIHGFWRKM-UHFFFAOYSA-N

Verwandte Kategorien

Allgemeine Beschreibung

Methylcyclopentadienyl manganese tricarbonyl (MMT) is commonly used as an antiknock agent in gasoline. It is also used as an additive in unleaded gasoline.

Anwendung

Methylcyclopentadienyl manganese tricarbonyl can be used for doping of ZnSe nanocrystals.
It can also be used as a reactant for:
  • Aldol addition reactions.
  • Preparation of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units.
  • Molecular fragmentation using shaped femtosecond laser pulses.
  • Preparation of MnAs thin films grown on GaAs(001) by metalorganic vapour phase epitaxy (MOVPE).

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Irrit. 2 - STOT RE 1 Inhalation

Zielorgane

Lungs

Lagerklassenschlüssel

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

204.8 °F - closed cup

Flammpunkt (°C)

96 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

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Die Dokumentenbibliothek aufrufen

Afsaneh Nouri et al.
International journal of biological macromolecules, 109, 1219-1231 (2017-11-25)
Montmorillonite -copper oxide (MMT-CuO) nanocomposites were prepared by a facile and eco-friendly method and introduced into chitosan (Cs) matrix to enhance its optical, mechanical and antibacterial properties. The synthesized composites were characterized using diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD)
Properties of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units
Landman, M.; et al.
Inorgorganica Chimica Acta, 363, 705-705 (2010)
Einat Peles et al.
The world journal of biological psychiatry : the official journal of the World Federation of Societies of Biological Psychiatry, 15(8), 620-628 (2014-03-29)
Methadone maintenance treatment (MMT) patients may achieve up to a 2-week privilege of methadone take-home doses (THD), which is associated with considerable responsibility. MMT patients are characterized as having poor sleep quality and low cognitive states. We studied sleep indices
Nacéra Boudia et al.
The Science of the total environment, 366(1), 143-147 (2005-11-22)
Methylcyclopentadienyl manganese tricarbonyl (MMT) is an organic derivative of manganese (Mn), used since 1976 in Canadian gasoline as an octane enhancer. Its combustion leads to the emission of Mn particles. Several studies carried out by our research group have established
Vadim V Lozovoy et al.
The journal of physical chemistry. A, 112(17), 3789-3812 (2008-04-25)
The possibility that chemical reactions may be controlled by tailored femtosecond laser pulses has inspired recent studies that take advantage of their short pulse duration, comparable to intramolecular dynamics, and high peak intensity to fragment and ionize molecules. In this
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