299685

Palladium(II)-trifluoracetat

97%

• Synonym(e): Trifluoressigsäure Palladium(II)-salz
• Lineare Formel: (CF₃COO)₂Pd
• CAS-Nummer: 42196-31-6
• Molekulargewicht: 332.45
• MDL-Nummer: MFCD00013204
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24858054
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 97%
• Form: solid
• Eignung der Reaktion: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: C-H Activation
• mp (Schmelzpunkt): ~220 °C
• SMILES String: FC(F)(F)C(=O)O[Pd]OC(=O)C(F)(F)F
• InChI: 1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2
• InChIKey: PBDBXAQKXCXZCJ-UHFFFAOYSA-L

Beschreibung

Allgemeine Beschreibung

Palladium(II) trifluoroacetate is a catalyst used in Suzuki-Miyaura, Heck, and Stille cross-coupling reactions.

Anwendung

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyst used for the mild decarboxylation of electron-rich aromatic acids and the direct cross-coupling of unactivated arenes.

Catalyzes the selective allylic oxidation of geranylacetone and other olefins to their allyl acetates, which can then be converted to keto alcohols.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves