299685

Palladium(II)-trifluoracetat

97%

• Synonym(e): Trifluoressigsäure Palladium(II)-salz
• Lineare Formel: (CF₃COO)₂Pd
• CAS-Nummer: 42196-31-6
• Molekulargewicht: 332.45
• MDL-Nummer: MFCD00013204
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24858054
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 97%
• Form: solid
• Eignung der Reaktion: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: C-H Activation
• mp (Schmelzpunkt): ~220 °C
• SMILES String: FC(F)(F)C(=O)O[Pd]OC(=O)C(F)(F)F
• InChI: 1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2
• InChIKey: PBDBXAQKXCXZCJ-UHFFFAOYSA-L

Beschreibung

Allgemeine Beschreibung

Palladium(II) trifluoroacetate is a catalyst used in Suzuki-Miyaura, Heck, and Stille cross-coupling reactions.

Anwendung

Catalyst used for the mild decarboxylation of electron-rich aromatic acids and the direct cross-coupling of unactivated arenes.

Catalyzes the selective allylic oxidation of geranylacetone and other olefins to their allyl acetates, which can then be converted to keto alcohols.

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves