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217247

Sigma-Aldrich

Sodium thiosulfate pentahydrate

ACS reagent, ≥99.5%

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About This Item

Fórmula linear:
Na2S2O3 · 5H2O
Número CAS:
Peso molecular:
248.18
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.21

grau

ACS reagent

Agency

suitable for EPA 1621
suitable for ISO 25101
suitable for SM 2310
suitable for SM 2320
suitable for SM 4500 - NH3

Ensaio

≥99.5%

forma

crystalline powder
crystals
pellets

Impurezas

≤0.002% N compounds
≤0.005% insolubles

pH

6.0-8.4 (25 °C, 5%)

solubilidade

water: soluble(lit.)

traços de ânion

S2-: passes test
SO42- and SO32-: ≤0.1%

traços de cátion

N: ≤0.002%

cadeia de caracteres SMILES

O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=S

InChI

1S/2Na.H2O3S2.5H2O/c;;1-5(2,3)4;;;;;/h;;(H2,1,2,3,4);5*1H2/q2*+1;;;;;;/p-2

chave InChI

PODWXQQNRWNDGD-UHFFFAOYSA-L

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Descrição geral

Sodium thiosulfate pentahydrate is a hydrated form of sodium thiosulfate. It is used as a sulfur source for the preparation of various organosulfur compounds.

Aplicação

Applied in a widely useful, thiosulfate-assisted, synthesis of a variety of diamine-CuCN complexes.
Sodium thiosulfate pentahydrate can be used as a sulfur source to synthesize:      
  • Thioester derivatives via one-pot two-step reactions with organic halides and aryl anhydrides.      
  • Sulfur nanoparticles using F. benghalensis leaf extract which acts as a reducing and capping agent.      
  • Unsymmetrical heteroaryl thioethers via multicomponent reaction with heteroaryl chlorides and alcohols.

It can also be used in the fabrication of microencapsulated phase change materials for thermal energy storage applications.

Características e benefícios

Na2S2O3 5H2O is a low toxic and odorless reagent that can be easily used in large-scale operations.

Código de classe de armazenamento

13 - Non Combustible Solids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


Certificados de análise (COA)

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Nuclear magnetic resonance in sodium thiosulfate pentahydrate.
Murty CRK and El Saffar ZM.
Acta Crystallographica, 15(6), 536-538 (1962)
Sodium thiosulfate pentahydrate: a redetermination by neutron diffraction.
Lisensky GC and Levy HA.
Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials, 34(6), 1975-1977 (1978)
Fingerprint imaging by scanning electrochemical microscopy.
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Electrochemical Communications, 9(7), 1778-1782 (2007)
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Inorganic chemistry, 38(5), 984-991 (2001-10-24)
A new synthetic procedure developed recently in our laboratories has made possible the synthesis of variety of new complexes of CuCN with diamines. Synthesis was effected by adding the ligand to a solution of CuCN in aqueous sodium thiosulfate. This
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