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Key Documents

12849

Sigma-Aldrich

Sulfato de cobre(II)

puriss., suitable for, meets analytical specification of Ph. Eur., BP, USP,FCC

Sinônimo(s):

Sulfato cúprico, Ácido sulfúrico, sal de cobre(II) (1:1) pentaidratado

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About This Item

Fórmula linear:
CuSO4 · 5H2O
Número CAS:
Peso molecular:
249.69
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.21

pressão de vapor

7.3 mmHg ( 25 °C)

Nível de qualidade

grau

puriss.

Ensaio

98.5-100.5% (USP)

forma

crystals

qualidade

meets analytical specification of Ph. Eur., BP, USP,FCC

perda

35.0-36.5% loss on drying, 250 °C

pH

3.5-4.5 (20 °C, 50 g/L)

pf

110 °C (dec.) (lit.)

traços de ânion

chloride (Cl-): ≤100 mg/kg

traços de cátion

As: ≤5 mg/kg
Ca: ≤50 mg/kg
Fe: ≤30 mg/kg
K: ≤100 mg/kg
Mg: ≤50 mg/kg
Na: ≤200 mg/kg
Ni: ≤50 mg/kg
Pb: 4 ppm

adequação

passes test for appearance of solution
suitable for

cadeia de caracteres SMILES

O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O

InChI

1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2

chave InChI

JZCCFEFSEZPSOG-UHFFFAOYSA-L

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Descrição geral

Copper(II) sulfate pentahydrate (CuSO4·5H2O, blue vitriol) is a hydrated copper(II) salt. It undergoes hydrothermal reactions with the tripodal ligands to afford metal-organic frameworks (MOFs). CuSO4·5H2O along with metallic copper was employed as catalyst for the synthesis of different ligand-arm functionalized azoamides. On heating above 560°C, it decomposes to CuO.

Aplicação

Copper(II) sulfate pentahydrate may be employed for the following studies:
  • As catalyst for the acetylation of alcohols and phenols under solvent-free conditions.
  • To compose the electrolyte for the electrodeposition of Cu-Zn-Sn precursors, required for the preparation of Cu2ZnSnS4 (CZTS) thin films.
  • As catalyst for the dehydration of alcohols.

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Código de classe de armazenamento

13 - Non Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


Certificados de análise (COA)

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Three novel metal-organic frameworks (MOFs), [Cu(1)SO4].H2O (4), [Cu2(2)2(SO4)2].4H2O (5) and [Cu(3)(H2O)]SO4.5.5H2O (6), were obtained by hydrothermal reactions of CuSO4.5H2O with the corresponding ligands, which have different flexibility. The structures of the synthesized complexes were determined by single-crystal X-ray diffraction analyses.
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