937037

cataCXium A Pd G4 ChemBeads

• Sinônimo(s): cataCXium Pd G4, [di(adamantan-1-yl)(butyl)phosphine](methanesulfonato-κO)[2′-(methylamino)-2-biphenylyl]palladium
• Fórmula empírica (Notação de Hill): C₃₈H₅₄NO₃PPdS
• Número CAS: 2230788-67-5
• Peso molecular: 742.30
• Código UNSPSC: 12352100

Propriedades

• forma: solid
• Nível de qualidade: 100
• composição: , 4-6 wt. % (loading of catalyst)
• adequação da reação: reagent type: catalyst; core: palladium; reaction type: Cross Couplings
• cadeia de caracteres SMILES: CCCCP([C@@]12C[C@H]3C[C@@H](C1)C[C@@H](C2)C3)[C@@]4(C5)C[C@H]6C[C@H](C[C@@H]5C6)C4.CNC7=C(C8=CC=CC=C8[Pd]OS(C)(=O)=O)C=CC=C7
• InChI: 1S/C24H39P.C13H12N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h17-22H,2-16H2,1H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1
• chave InChI: ROZFJYIWIVSDBR-UHFFFAOYSA-M

Descrição

Descrição geral

A fourth generation (G4) Buchwald precatalyst on glass beads that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents.

Aplicação

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
For general uses, product is also available in powdered form (900349)

Características e benefícios

For feature and benefits, please visit the technical article on Buchwald G4 Precatalysts. https://www.sigmaaldrich.com/US/en/technical-documents/technical-article/chemistry-and-synthesis/cross-coupling/g3-and-g4-buchwald-precatalysts