ALD00617

(−)-PI Reagent

≥95%

• Sinônimo(s): (2R,3aS,5R,7aS)-7a-Methyl-2-((perfluorophenyl)thio)-5-(prop-1-en-2-yl)hexahydrobenzo[d][1,3,2]oxathiaphosphole 2-sulfide, Phosphorus Incorporation reagent
• Fórmula empírica (Notação de Hill): C₁₆H₁₆F₅OPS₃
• Número CAS: 2269472-45-7
• Peso molecular: 446.46
• Número MDL: MFCD34549926
• Código UNSPSC: 12352005
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: ≥95%
• Formulário: powder
• pf: 118-123 °C
• cadeia de caracteres SMILES: Fc1c(c(c(c(c1F)F)S[P]2(=S)S[C@@H]3[C@@](O2)(CC[C@H](C3)C(=C)C)C)F)F
• InChI: 1S/C16H16F5OPS3/c1-7(2)8-4-5-16(3)9(6-8)25-23(24,22-16)26-15-13(20)11(18)10(17)12(19)14(15)21/h8-9H,1,4-6H2,2-3H3/t8-,9+,16+,23?/m1/s1
• chave InChI: CZCFCQOKUBIPHN-QSHUGKRNSA-N

Descrição

Aplicação

(−)-PI Reagent is an air- and moisture-tolerant, reagent developed in the Baran lab for stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides. The enantiomer, (+)-PI Reagent, is also available.

Learn more about PI and PSI reagents

Outras notas

Enantiodivergent formation of C-P bonds: synthesis of P-chiral phosphines and methyl-phosphonate oligonucleotides

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable