A24109
Acryloyl chloride
≥97%, contains ~400 ppm phenothiazine as stabilizer
Sinônimo(s):
Acrylic acid chloride, prop-2-enoyl chloride, 2-Propenoyl chloride
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About This Item
Fórmula linear:
CH2=CHCOCl
Número CAS:
Peso molecular:
90.51
Beilstein:
635744
Número CE:
Número MDL:
Código UNSPSC:
12162002
ID de substância PubChem:
NACRES:
NA.23
Produtos recomendados
densidade de vapor
>1 (vs air)
Nível de qualidade
pressão de vapor
1.93 psi ( 20 °C)
Ensaio
≥97%
forma
liquid
contém
~400 ppm phenothiazine as stabilizer
índice de refração
n20/D 1.435 (lit.)
pb
72-76 °C (lit.)
densidade
1.114 g/mL at 25 °C (lit.)
temperatura de armazenamento
2-8°C
cadeia de caracteres SMILES
ClC(=O)C=C
InChI
1S/C3H3ClO/c1-2-3(4)5/h2H,1H2
chave InChI
HFBMWMNUJJDEQZ-UHFFFAOYSA-N
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Descrição geral
Acryloyl chloride, an organic chemical compound, serves primarily as a reactive monomer for synthesizing polymers and copolymers applicable in diverse fields like adhesives, coatings, hydrogel coatings, sustained drug release, hydrogel film, organic electronic devices and plastics. Phenothiazine is commonly used as a stabilizer for acryloyl chloride during polymerization. It is added in small quantities (400ppm), to prevent the formation of unwanted by-products and to extend the shelf life of the reactive monomer. It also acts as a scavenger for free radicals that may form during the polymerization process.
Aplicação
Acryloyl chloride can be used as:
- A monomer to synthesize crosslinked zwitterionic hydrogel coatings for sensing and detection in complex media.
- A reactant to synthesize crosslinked hydrogel film by reacting with a hydrophilic monomer called N,N-(dimethylacrylamide) (DMAA). The prepared hydrogel film is further used in sustained drug delivery.
- A monomer in the preparation of acrylate-based polymers with excellent n-type semiconducting properties, which are important for the development of organic electronic devices.
- The cyclam monomer. The polymer of this modified cyclam monomer can be used in specific transition metal binding.
Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1A
Perigos de suplementos
Código de classe de armazenamento
3 - Flammable liquids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
30.2 °F
Ponto de fulgor (°C)
-1 °C
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An automated procedure for the radiosynthesis of the labeling synthon [11C]acryloyl chloride was developed and applied for labeling several N-acryl amides with carbon-11. [11C]-6-acrylamido-4-(3,4-dichloro-6-fluoroanilino)quinazoline (ML03), a novel PET biomarker targeting the epidermal growth factor receptor tyrosine kinase (EGFr-TK) in cancer
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Copolymers of acrylated derivatives of alpha-chymotrypsin and polyethylene glycol (PEG) have been prepared and used as biocatalysts for the synthesis of model peptides in organic solvent containing a low quantity of water. Other peptide couplings have been tried to point
J C Tiller et al.
Proceedings of the National Academy of Sciences of the United States of America, 98(11), 5981-5985 (2001-05-17)
Poly(4-vinyl-N-alkylpyridinium bromide) was covalently attached to glass slides to create a surface that kills airborne bacteria on contact. The antibacterial properties were assessed by spraying aqueous suspensions of bacterial cells on the surface, followed by air drying and counting the
Combined CASSCF and MR-CI study on photoinduced dissociation and isomerization of acryloyl chloride.
Gang-Long Cui et al.
The journal of physical chemistry. A, 110(42), 11839-11846 (2006-10-20)
The potential energy surfaces of isomerization and dissociation reactions for CH2CHCOCl in the S0, T1, T2, and S1 states have been mapped with DFT, CASSCF, MP2, and MR-CI calculations. Rate constants for adiabatic and nonadiabatic processes have been calculated with
R Bahulekar et al.
Biomaterials, 20(4), 357-362 (1999-02-27)
Poly(N-alkyl mono and disubstituted) acrylamide derivatives were synthesized from poly(acryloyl chloride) by monomer analogous reaction. The polymers were characterized by FTIR-ATR and GPC. The contact angle measurements were performed to evaluate hydrophobic/hydrophilic characters of these polymers. The N-alkyl substituents changed
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