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Merck
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Key Documents

796034

Sigma-Aldrich

Óxido de grafeno

powder, 15-20 sheets, 4-10% edge-oxidized, avg. no. of layers, 15 ‑ 20

Sinônimo(s):

graphite oxide

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About This Item

Fórmula linear:
CxOyHz
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

Nível de qualidade

forma

powder

Características

avg. no. of layers 15 ‑ 20

solubilidade

water: dispersible (polar solvents)

densidade volumétrica

~1.8 g/cm3

cadeia de caracteres SMILES

O=C(O)C1C2=C3C4=C5C6=C7C8=C9C%10=C%11C(C%12=C%13C%10=C%14C8=C%15C6=C%16C4=C%17C2=CC(C(O)=O)C%18=C%17C%19=C%16C%20=C%15C%21=C%14C%22=C%13C(C%23=C%24C%22=C%25C%21=C%26C%20=C%27C%19=C%28C%18=CC(C(O)=O)C%29=C%28C%30=C%27C%31=C%26C%32=C%25C%33=C%24C(C%34=C%35C

InChI

1S/C140H42O20/c141-131(142)26-13-23-15-44-62(140(159)160)45-16-24-14-40-31(132(143)144)5-1-29-41-20-48(135(149)150)56-33-7-3-28-27-2-6-32-55-37(133(145)146)11-9-35-60(138(155)156)42-17-25-18-43-61(139(157)158)36-10-12-38(134(147)148)58-46-21-50(137(153)154)59-47-22-49(136(151)152)57-34-8-4-30-39(19-26)51(23)78-72(44)88-75(45)80-52(24)79(54(29)40)95-71(41)83(56)101-93-69(33)64(28)91-90-63(27)68(32)92-86(66(35)55)73(42)81-53(25)82-74(43)87(67(36)58)96-76(46)85(59)103-97-77(47)84(57)102-94-70(34)65(30)89(78)105-104(88)115-98(80)111(95)116(101)126-122-110(93)107(91)120-119-106(90)108(92)99(81)114-100(82)112(96)118(103)128(124(114)119)123-113(97)117(102)127(130(122)129(120)123)121(109(94)105)125(115)126/h2,5,7-10,12-22,26,38,48-50H,1,3-4,6,11H2,(H,141,142)(H,143,144)(H,145,146)(H,147,148)(H,149,150)(H,151,152)(H,153,154)(H,155,156)(H,157,158)(H,159,160)

chave InChI

VTWITIAIMADGRM-UHFFFAOYSA-N

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Descrição geral

  • Form: Brown/Black powder
  • Bulk Density: ~1.8 g/cm3
  • Solubility: Dispersible in water and polar solvents
  • Number of layers: 15-20
  • Oxidation: 4-10%
The material basically consists of exfoliated graphene nanoplatelets containing functional organic groups. The oxygen content is less than 5%; the majority groups are hydroxyls (OH), which enables further chemical modifications to add new functionalities. The functionalization approach was designed to attach most of the groups on the border of the foils, aiming to preserve the intrinsic properties of graphene (e.g.: electric conductivity).

Aplicação

The product is aimed for dispersion and/or incorporation in polar solvents (e.g.: water, THF and DMF) and polar polymeric matrices (e.g.: PLA, PA and PET). It is suitable for in situ polymerization, direct resin mixing and molding, solvent dissolution, extrusion processing after incorporation. Potential applications include:
  • Nanocomposites [1,2]
  • Anti-corrosion coatings [3,4]
  • Films with barrier properties [5,6]
  • Membranes for separation [7,8]
  • Conductive inks [9,10]
  • Energy storage [11,12]

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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Artigos

Carbon nanomaterials (CNMs), such as single-walled carbon nanotubes (SWCNTs), multi-walled carbon nanotubes (MWCNTs), and graphene (Figure 1), have diverse commercial applications including lighter and stronger composite materials, improved energy storage devices, more sensitive sensors, and smaller transistors.

Since its discovery little more than a decade ago,1 the two-dimensional (2D) allotrope of carbon—graphene—has been the subject of intense multidisciplinary research efforts.

Graphene is a one-atomic-layer thick two-dimensional material made of carbon atoms arranged in a honeycomb structure. Its fascinating electrical, optical, and mechanical properties ignited enormous interdisciplinary interest from the physics, chemistry, and materials science fields.

Advanced technologies for energy conversion and storage are widely sought after for their potential to improve consumer and electronic device performance as well as for the prospect of reducing the societal and environmental impact of energy generation.

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