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Sigma-Aldrich

Borane dimethyl sulfide complex solution

greener alternative

1.0 M in 2-methyltetrahydrofuran

Sinônimo(s):

BMS, Trihydro[thiobis[methane]]boron

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About This Item

Fórmula linear:
(CH3)2S · BH3
Número CAS:
13292-87-0
Peso molecular:
75.97
Beilstein:
3663489
Número MDL:
MFCD00013189
Código UNSPSC:
12352112
ID de substância PubChem:
329767736
NACRES:
NA.22

Formulário

liquid

adequação da reação

reagent type: reductant

características do produto alternativo mais ecológico

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentração

1.0 M in 2-methyltetrahydrofuran

densidade

0.844 g/mL at 25 °C

grupo funcional

thioether

categoria alternativa mais ecológica

, Aligned

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

B.CSC

InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

chave InChI

RMHDLBZYPISZOI-UHFFFAOYSA-N

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Descrição geral

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here.

Aplicação

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Commonly used in hydroboration of olefins and as a reductant of carbonyls. 2-Me-THF has shown potential as an environmentally friendly solvent compared to commonly used solvents; e.g. dichloromethane and THF.
For an alternative to Tetrahydrofuran and Dichloromethane, please see: An alternative to Tetrahydrofuran and Dichloromethane
Reactant used as a regioselective reducing agent

Reactant involved in:
  • Hydroboration / oxidation
Synthesis of cage compounds

Embalagem

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Informações legais

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - Water-react 1

Perigos de suplementos

EUH019

Código de classe de armazenamento

4.3 - Hazardous materials which set free flammable gases upon contact with water

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

9.3 °F

Ponto de fulgor (°C)

-12.6 °C

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Certificados de análise (COA)

Lot/Batch Number
SHBL6342
SHBK2868
SHBJ1749
SHBG1668V
SHBC9981

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Se precisar de uma versão específica, você pode procurar um certificado específico pelo número do lote ou da remessa.

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