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Key Documents

688738

Sigma-Aldrich

Basolite® A100

greener alternative

produced by BASF

Sinônimo(s):

Aluminum terephthalate, MIL-53(Al)

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About This Item

Fórmula empírica (Notação de Hill):
C8H5AlO5
Peso molecular:
208.10
Código UNSPSC:
26111700
NACRES:
NA.23

grau

produced by BASF

forma

tablet

características do produto alternativo mais ecológico

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

área da superfície

1100-1500 m2/g

Distribuição do tamanho da partícula

31.55 μm (D50)

densidade volumétrica

0.4 g/cm3

categoria alternativa mais ecológica

, Enabling

Descrição geral

Basolite (TM) A100 is also known as MIL-53(Al). It is an ultramicroporous metal framework (MOF).
Basolite®A100 is a microporous metal-organic framework (MOF), which consists of three-dimensional networks with micropores up to 900 pm in diameter. It has characteristics that are identical to MIL-53(Al) as it contains octahedral AlO4(OH)2 units connected through 1,4-benzenedicarboxylate ligands. It allows the formation of a framework with a high specific surface of 1084 m2g-1 area and a pore volume of about 0.51 cm2g-1.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Aplicação

Basolite (TM) A100 was used in the separation of C8-alkylaromatic compounds.
Basolite®A100 is majorly used in the binary gas separation of CO2/CH4 and CO2/N2. It can also be used for gas adsorption (hydrogen gas) and for the supercritical adsorption of CO2.

Outras notas

can be reactivated at 200°C (vacuum)

Informações legais

Basolite is a registered trademark of BASF SE

Pictogramas

Health hazardExclamation mark
GHS08,GHS07

Palavra indicadora

Danger

Frases de perigo

H319,H360D

Classificações de perigo

Eye Irrit. 2 - Repr. 1B

Código de classe de armazenamento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number
STBG5839V
STBC4615V
S45326

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731706

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Gérard Férey et al.
Chemical communications (Cambridge, England), (24), 2976-2977 (2004-01-06)
Hydrogen adsorption has been studied in the nanoporous metal-benzenedicarboxylate M(OH)(O2C-C6H4-CO2) (M = Al3+, Cr3+); these solids show a hydrogen storage capacity of 3.8 and 3.1 wt.% respectively when loaded at 77 K under 1.6 MPa.
A complete procedure for acidic gas separation by adsorption on MIL-53 (Al)
Heymans N, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 154(1), 93-99 (2012)
Christian Serre et al.
Journal of the American Chemical Society, 124(45), 13519-13526 (2002-11-07)
The first three-dimensional chromium(III) dicarboxylate, MIL-53as or Cr(III)(OH) x [O(2)C-C(6)H(4)-CO(2)].[HO(2)C-C(6)H(4)-CO(2)H](0.75), has been obtained under hydrothermal conditions (as: as-synthesized). The free acid can be removed by calcination giving the resulting solid, MIL-53ht or Cr(III)(OH) x [O(2)C-C(6)H(4)-CO(2)]. At room temperature, MIL-53ht adsorbs
A combined computational and experimental study of high pressure and supercritical CO2 adsorption on Basolite MOFs
Deniz E, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 175(1), 34-42 (2013)
MOF-containing mixed-matrix membranes for CO2/CH4 and CO2/N2 binary gas mixture separations
Basu S, et al.
Separation and Purification Technology, 81(1), 31-40 (2011)
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