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Documentos Principais

679259

Sigma-Aldrich

Tetramethyl orthosilicate

deposition grade, ≥98%, ≥99.9% trace metals basis

Sinônimo(s):

Tetramethoxysilane

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About This Item

Fórmula linear:
Si(OCH3)4
Número CAS:
Peso molecular:
152.22
Beilstein:
1699658
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

grau

deposition grade

densidade de vapor

5.25 (vs air)

pressão de vapor

13 hPa ( 20 °C)

Ensaio

≥98%
≥99.9% trace metals basis

forma

liquid

índice de refração

n20/D 1.368 (lit.)

pb

121-122 °C (lit.)

pf

−4 °C (lit.)

densidade

1.023 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

CO[Si](OC)(OC)OC

InChI

1S/C4H12O4Si/c1-5-9(6-2,7-3)8-4/h1-4H3

chave InChI

LFQCEHFDDXELDD-UHFFFAOYSA-N

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Aplicação

Used in the sol-gel synthesis of chromium-doped silicates and in the formation of hexagonal mesoporous silica layers.

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 1 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

78.8 °F - closed cup

Ponto de fulgor (°C)

26 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Yun Tian et al.
Electrophoresis, 29(4), 960-970 (2008-01-24)
A novel calix[4] open-chain crown ether (p-tert-butylcalix[4]arene-1,3-bis(allyloxyethy) ether)-modified, organic-inorganic hybrid silica-based monolithic column possessing vinyl ligands for CEC is described. The monolithic silica matrix containing a vinyl functionality was synthesized by in situ cocondensation of tetramethoxysilane (TMOS) and vinyltrimethoxysilane (VTMS)
Yonghao Xiu et al.
Journal of colloid and interface science, 326(2), 465-470 (2008-07-29)
A method for the preparation of inorganic superhydrophobic silica coatings using sol-gel processing with tetramethoxysilane and isobutyltrimethoxysilane as precursors is described. Incorporation of isobutyltrimethoxysilane into silica layers resulted in the existence of hydrophobic isobutyl surface groups, thereby generating surface hydrophobicity.
Josef Planeta et al.
Journal of chromatography. A, 1217(36), 5737-5740 (2010-08-03)
The temperature effects during the sol-gel process and ageing of the silica-based monolith on the structure and separation efficiency of the capillary columns (100microm i.d., 150mm) for HPLC separations were studied. The tested columns were synthesized from a mixture of
Yan Fang et al.
Journal of chromatography. A, 1217(41), 6405-6412 (2010-09-03)
A simple capillary flow porometer (CFP) was assembled for through-pore structure characterization of monolithic capillary liquid chromatography columns in their original chromatographic forms. Determination of differential pressures and flow rates through dry and wet short capillary segments provided necessary information
Shota Miyazaki et al.
Journal of chromatography. A, 1218(15), 1988-1994 (2010-12-24)
Chromatographic properties of a new type of monolithic silica rod columns were examined. Silica rod columns employed for the study were prepared from tetramethoxysilane, modified with octadecylsilyl moieties, and encased in a stainless-steel protective column with two polymer layers between

Artigos

From Form to Function: Molding Porous Materials in Three Dimensions by Colloidal Crystal Templating

Deposition Grade Silanes, fully characterized by chemical analysis and nuclear magnetic resonance (NMR) with greater than 98% purity, for Sol-Gel Processes.

Mesoporous Oxides and Their Applications to Hydrogen Storage

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