56655

(−)-Methyl (R)-3-hydroxyvalerate

≥98.0% (sum of enantiomers, GC)

• Sinônimo(s): (−)-Methyl (R)-3-hydroxypentanoate
• Fórmula empírica (Notação de Hill): C₆H₁₂O₃
• Número CAS: 60793-22-8
• Peso molecular: 132.16
• Beilstein: 4655380
• Número MDL: MFCD00077796
• Código UNSPSC: 12352108
• ID de substância PubChem: 57651591
• NACRES: NA.22

Propriedades

• Ensaio: ≥98.0% (sum of enantiomers, GC)
• atividade óptica: [α]20/D −37±3°, c = 1% in chloroform
• índice de refração: n20/D 1.427
• p.e.: 68-70 °C/5 mmHg (lit.)
• densidade: 1.029 g/mL at 20 °C (lit.)
• grupo funcional: ester; hydroxyl
• cadeia de caracteres SMILES: CC[C@@H](O)CC(=O)OC
• InChI: 1S/C6H12O3/c1-3-5(7)4-6(8)9-2/h5,7H,3-4H2,1-2H3/t5-/m1/s1
• chave InChI: XHFXKKFVUDJSPJ-RXMQYKEDSA-N

Descrição

Aplicação

• Preparation of single-enantiomer 2-methyl-4-heptanol, a pheromone of Metamasius hemipterus, using (S)-2-methoxy-2-(1-naphthyl)propionic acid.: This research outlines the synthesis of a single-enantiomer pheromone compound using (S)-2-methoxy-2-(1-naphthyl)propionic acid. The process highlights the importance of enantiopure intermediates like (−)-Methyl (R)-3-hydroxyvalerate in the synthesis of biologically active compounds (Ichikawa and Ono, 2006).

Outras notas

Chiral building block for EPC syntheses; selective anti-alkylation of its dianion; OH protection and reduction of ester group to aldehyde or alcohol functions; stereoselective preparation of a dioxanone with pivalaldehyde

Informações de segurança

• Código de classe de armazenamento: 10 - Combustible liquids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 168.8 °F - closed cup
• Ponto de fulgor (°C): 76 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Gloves, type ABEK (EN14387) respirator filter