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Key Documents

339164

Sigma-Aldrich

Bis(cyclopentadienyl)cobalt(II)

Sinônimo(s):

Cobaltocene

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About This Item

Fórmula linear:
Co(C5H5)2
Número CAS:
Peso molecular:
189.12
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

forma

powder or crystals
solid

Nível de qualidade

adequação da reação

core: cobalt

pf

176-180 °C (dec.) (lit.)

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

[Co].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.Co/c2*1-2-4-5-3-1;/h2*1-5H;

chave InChI

PXFGMRZPRDJDEK-UHFFFAOYSA-N

Descrição geral

Bis(cyclopentadienyl)cobalt(II) also known as cobaltocene, is an organometalliccompound that is widely used in the field of polymer synthesis, cobaltnanomaterials, and redox flow batteries.

Aplicação

Bis(cyclopentadienyl)cobalt(II) can be used:
  • As a dopant to prepare encapsulated carbon nanotubes with high thermoelectric conversion efficiency.
  • As a CVD precursor to fabricate cobalt oxide thin films for various applications.
  • As a redox-active anode species in Li-based redox flow batteries to achieve higher energy densities and energy efficiencies.
  • As a catalyst for controlled/“living” radical polymerization of methylmethacrylate.

Pictogramas

FlameHealth hazard

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Carc. 2 - Flam. Sol. 2 - Muta. 2 - Resp. Sens. 1 - Skin Sens. 1

Código de classe de armazenamento

4.1B - Flammable solid hazardous materials

Classe de risco de água (WGK)

WGK 3

Equipamento de proteção individual

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Journal of the American Chemical Society, 140(42), 13753-13763 (2018-09-27)
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