29511

(S)-(−)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)

≥97%, optical purity ee: ≥99%

• Sinônimo(s): (S)-(−)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl, (S)-(−)-MeO-BIPHEP, SL-A101-2
• Fórmula empírica (Notação de Hill): C₃₈H₃₂O₂P₂
• Número CAS: 133545-17-2
• Peso molecular: 582.61
• Beilstein: 4790083
• Número MDL: MFCD03095430
• Código UNSPSC: 12352112
• ID de substância PubChem: 24857759
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: ≥97%
• pureza óptica: ee: ≥99%
• características do produto alternativo mais ecológico: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• grupo funcional: phosphine
• categoria alternativa mais ecológica: Aligned,
• cadeia de caracteres SMILES: COc1cccc(P(c2ccccc2)c3ccccc3)c1-c4c(OC)cccc4P(c5ccccc5)c6ccccc6
• InChI: 1S/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
• chave InChI: KRJVQCZJJSUHHO-UHFFFAOYSA-N

Descrição

Descrição geral

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicação

Atropisomeric MeOBIPHEP ligands

• C–C coupling reactions
• Ligand for palladium-catalyzed intramolecular allylic alkylation of unsaturated amides
• Enantioselective hydrogenation of a-amino-ß-keto ester hydrochlorides catalyzed by an iridium complex
• Asymmetric hydrogenation of aromatic ketones

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

Embalagem

Bottomless glass bottle. Contents are inside inserted fused cone.

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)