155039

Diphenyl(p-tolyl)phosphine

96%

• Sinônimo(s): (4-Methylphenyl)diphenyl phosphine
• Fórmula linear: (C₆H₅)₂PC₆H₄CH₃
• Número CAS: 1031-93-2
• Peso molecular: 276.31
• Número CE: 213-848-3
• Número MDL: MFCD00008543
• Código UNSPSC: 12352002
• ID de substância PubChem: 24849330
• NACRES: NA.22

Propriedades

• Ensaio: 96%
• forma: liquid
• adequação da reação: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• pf: 66-68 °C (lit.)
• grupo funcional: phosphine
• cadeia de caracteres SMILES: Cc1ccc(cc1)P(c2ccccc2)c3ccccc3
• InChI: 1S/C19H17P/c1-16-12-14-19(15-13-16)20(17-8-4-2-5-9-17)18-10-6-3-7-11-18/h2-15H,1H3
• chave InChI: QJIMTLTYXBDJFC-UHFFFAOYSA-N

Descrição

Aplicação

Reactant for:

• Three-component cyclization
• Probing coordination ability via a palladium pincer complex
• Chelation-assisted hydroacylation of olefins with primary alcohols

Reactant for synthesis of:

• Trinuclear ruthenium carbonyl triarylphosphine cluster complexes
• Leishmanicidal leads targeting mitochondria through inhibition of the respiratory complex
• InP nanofibers / metal phosphide nanostructures
• Peroxyl radical cations via pulse radiolysis one-electron oxidations

Informações de segurança

• Pictogramas: GHS07
• Palavra indicadora: Warning
• Frases de perigo: H315,H319,H335
• Declarações de precaução: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classificações de perigo: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Respiratory system
• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: dust mask type N95 (US), Eyeshields, Gloves