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Merck
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Documentos

115150

Sigma-Aldrich

Thiophosgene

Sinônimo(s):

Thiocarbonyl chloride

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About This Item

Fórmula linear:
CSCl2
Número CAS:
463-71-8
Peso molecular:
114.98
Beilstein:
1633495
Número CE:
207-341-6
Número MDL:
MFCD00004918
Código UNSPSC:
12352000
eCl@ss:
38020402
ID de substância PubChem:
24847201
NACRES:
NA.22

densidade de vapor

4 (vs air)

Nível de qualidade

200

adequação da reação

reaction type: Carbonylations

índice de refração

n20/D 1.548 (lit.)

pb

70-75 °C (lit.)

densidade

1.50 g/mL at 20 °C (lit.)

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

ClC(Cl)=S

InChI

1S/CCl2S/c2-1(3)4

chave InChI

ZWZVWGITAAIFPS-UHFFFAOYSA-N

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Aplicação

Reagent used to prepare a bulky thiourea ligand for palladium-catalyzed aerobic oxidation of alcohols to aldehydes and ketones.

Pictogramas

Skull and crossbonesCorrosion
GHS06,GHS05

Palavra indicadora

Danger

Frases de perigo

H302,H315,H318,H331,H335

Classificações de perigo

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de risco de água (WGK)

WGK 1

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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W Kedzierski et al.
The Journal of chemical physics, 120(19), 9087-9089 (2004-07-23)
A special xenon matrix detector has been used to study the production of S(1S) following controlled electron impact on thiophosgene (Cl2CS) targets over an electron energy range from threshold to 400 eV. Time-of-flight spectroscopy has been used to measure S(1S)
Christof Jung et al.
The journal of physical chemistry. A, 110(16), 5317-5325 (2006-04-21)
The dispersed fluorescence spectrum of the ground electronic state of thiophosgene, SCCl2, is analyzed in a very complex region of vibrational excitation, 7000-9000 cm(-1). The final result is that most of the inferred excited vibrational levels are assigned in terms
Cheng Li et al.
Colloids and surfaces. B, Biointerfaces, 171, 159-166 (2018-07-22)
Dual mode imaging technology is widely developed to achieve the early-stage precision cancer diagnosis. Here we designed a dual-modal magnetic resonance/near infrared fluorescence optical imaging contrast agent (GdF-SS-NIR783) with the fluorescence activatable and safer gadofullerene. The nanoprobes were fabricated by
Youlia Hagooly et al.
The Journal of organic chemistry, 73(17), 6780-6783 (2008-08-13)
A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF3. The fluorination step is complete
T A Lewis et al.
Journal of bacteriology, 177(8), 2204-2208 (1995-04-01)
Pseudomonas sp. strain KC transforms carbon tetrachloride into carbon dioxide and nonvolatile products, without chloroform as an intermediate. To define the pathway for hydrolysis, nonvolatile products were analyzed. Condensation products containing the carbon atom of carbon tetrachloride as carbonyl and
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