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203440

Sigma-Aldrich

Indium(III) chloride

99.999% trace metals basis

Synonyme(s) :

Indium trichloride

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About This Item

Formule linéaire :
InCl3
Numéro CAS:
10025-82-8
Poids moléculaire :
221.18
Numéro CE :
233-043-0
Numéro MDL:
MFCD00011058
Code UNSPSC :
12352302
ID de substance PubChem :
24852172
Nomenclature NACRES :
NA.23

Pureté

99.999% trace metals basis

Forme

powder or flakes (or chunks)

Pertinence de la réaction

reagent type: catalyst
core: indium

Impuretés

≤15.0 ppm Trace Metal Analysis

Densité

3.46 g/mL at 25 °C (lit.)

Chaîne SMILES 

Cl[In](Cl)Cl

InChI

1S/3ClH.In/h3*1H;/q;;;+3/p-3

Clé InChI

PSCMQHVBLHHWTO-UHFFFAOYSA-K

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Description générale

Indium(III) chloride is a Lewis acid catalystused in a variety of organic reactions. It also finds application in the fields of catalysis, solar cells, and optoelectronics.

Application

Indium(III) chloride can be used:
  • As a catalyst for the preparation of 1,3-dithiolanes from aldehydes and ketones.
  • For acylation of phenols, thiols, alcohols, and amines.
  • As a precursor to fabricate Indium tin oxide(ITO) thin films for dye-sensitized solar cells.
  • To prepare solution-processed oxide semiconductor thin-film transistors (OS TFTs) that can be used in display devices.

Pictogrammes

Health hazardCorrosion
GHS08,GHS05

Mention d'avertissement

Danger

Mentions de danger

H314,H372,H412

Classification des risques

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C - STOT RE 1 Inhalation

Organes cibles

Lungs

Code de la classe de stockage

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificats d'analyse (COA)

Recherchez un Certificats d'analyse (COA) en saisissant le numéro de lot du produit. Les numéros de lot figurent sur l'étiquette du produit après les mots "Lot" ou "Batch".

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Consulter la Bibliothèque de documents

Mecheril Valsan Nandakumar et al.
Chemical communications (Cambridge, England), (26), 2756-2758 (2007-06-28)
The indium-bipyridine-catalyzed, enantioselective ring-opening of meso-epoxides with aliphatic and aromatic thiols furnished 1,2-mercapto alcohols in good yields and excellent enantioselectivities; the crystal structure of the chiral catalyst reveals a pentagonal-bipyramidal coordination geometry around the indium center.
Synthesis, 1712-1712 (2007)
Tetrahedron Letters, 48, 6743-6743 (2007)
Theresa A Proia et al.
Clinical cancer research : an official journal of the American Association for Cancer Research, 26(23), 6335-6349 (2020-09-19)
Danvatirsen is a therapeutic antisense oligonucleotide (ASO) that selectively targets STAT3 and has shown clinical activity in two phase I clinical studies. We interrogated the clinical mechanism of action using danvatirsen-treated patient samples and conducted back-translational studies to further elucidate
Naveen Mulakayala et al.
Bioorganic & medicinal chemistry letters, 22(15), 5063-5066 (2012-07-04)
A convenient and practical methodology for the synthesis of 2-aryl quinazolin-4(3H)-ones by the condensation of o-aminobenzamides with aromatic aldehydes under mild conditions using catalytic InCl(3) with good yields and high selectivities. This method has been extended for the synthesis of
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