Direkt zum Inhalt
Merck

Regioselective copolymerization of acryl sucrose monomers.

The Journal of organic chemistry (2004-10-23)
Maria Teresa Barros, Krasimira T Petrova, Ana Maria Ramos
ZUSAMMENFASSUNG

1',2,3,3',4,4',6-Hepta-O-benzyl-sucrose has been prepared and selectively 6'-O-esterified with small alpha,beta-unsaturated acid derivatives. New chiral copolymers containing sucrose have been synthesized by radical polymerization, and some of their physical properties have been determined.

MATERIALIEN
Produktnummer
Marke
Produktbeschreibung

Sigma-Aldrich
Saccharose, ≥99.5% (GC), BioXtra
Sigma-Aldrich
4-(Dimethylamino)-pyridin, ReagentPlus®, ≥99%
Sigma-Aldrich
N,N-Dimethylformamid, anhydrous, 99.8%
Sigma-Aldrich
Tetrabutylammoniumiodid, reagent grade, 98%
Sigma-Aldrich
tert-Butyl(chlor)diphenylsilan, 98%