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Merck

372145

Sigma-Aldrich

Trichlorethylen

anhydrous, contains 40 ppm diisopropylamine as stabilizer, ≥99%

Synonym(e):

TCE, Trichlorethen

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About This Item

Lineare Formel:
ClCH=CCl2
CAS-Nummer:
Molekulargewicht:
131.39
Beilstein:
1736782
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352101
PubChem Substanz-ID:
NACRES:
NA.21

Qualität

anhydrous

Qualitätsniveau

Dampfdichte

4.5 (vs air)

Dampfdruck

61 mmHg ( 20 °C)

Assay

≥99%

Form

liquid

Selbstzündungstemp.

770 °F

Enthält

40 ppm diisopropylamine as stabilizer

Verunreinigungen

<0.002% water
<0.005% water (100 mL pkg)

Abdampfrückstand

<0.0005%

Brechungsindex

n20/D 1.476 (lit.)

bp

86.7 °C (lit.)

mp (Schmelzpunkt)

−84.8 °C (lit.)

Dichte

1.463 g/mL at 25 °C (lit.)

SMILES String

Cl\C=C(\Cl)Cl

InChI

1S/C2HCl3/c3-1-2(4)5/h1H

InChIKey

XSTXAVWGXDQKEL-UHFFFAOYSA-N

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Allgemeine Beschreibung

Trichloroethylene (TCE) is a chlorinated ethylene compound commonly used as a dry cleaning and degreasing solvent. Without stabilizers, TCE is unstable and degrades easily in the presence of moisture air, light and heat, it can be minimized by adding diisopropylamine as a stabilizer. Various methods have been reported for its synthesis. One of them is by chlorinating ethylene dichloride. Since TCE is one of the most common industrial solvent it has led it to be a major contaminant found in the ground water. It has adverse effect on human health due to its potential toxicity and carcinogenicity. Its toxicity and carcinogenicity has been studied.
Many methods have been proposed for the mineralization of TCE.

Piktogramme

Health hazardExclamation mark

Signalwort

Danger

Gefahreneinstufungen

Aquatic Chronic 3 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Zielorgane

Central nervous system

Lagerklassenschlüssel

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

closed cup - does not flash

Flammpunkt (°C)

closed cup - does not flash

Persönliche Schutzausrüstung

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


Zulassungslistungen

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EU REACH SVHC Candidate List

CAS No.

EU REACH Annex XVII (Restriction List)

CAS No.

EU REACH Annex XIV (Authorisation List)

CAS No.

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Analysenzertifikate (COA)

Lot/Batch Number

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S Yamazaki et al.
Water research, 35(4), 1022-1028 (2001-03-10)
A recirculating system of aqueous trichloroethylene (TCE) solutions through the packed bed reactor with TiO2 pellets has been developed in order to mineralize TCE without difficulties for filtration and recovery of catalyst. The TiO2 pellets prepared by sol gel method
Anaerobic degradation of trichloroethylene in soil.
Kleopfer RD, et al.
Environmental Science & Technology, 19(3), 277-280 (1985)
E M Waters et al.
Journal of toxicology and environmental health, 2(3), 671-707 (1977-01-01)
Trichloroethylene (TCE) has been an industrial chemical of some importance for the past 50 years. First synthesized by Fischer in 1864, TCE has enjoyed considerable industrial usage as a degreaser and limited medical use as an inhalation anesthetic and analgesic.
Chlorinated Decreasing Solvents: Physical-Chemical Properties Affecting Aquifer Contamination and Remediation.
Jackson RE and Dwarakanath V.
Ground Water Monitoring & Remediation, 19(4), 102-110 (1999)
A L Teel et al.
Water research, 35(4), 977-984 (2001-03-10)
Contaminant degradation, stoichiometry, and role of hydroxyl radicals (OH*) in four Fenton's systems were investigated using trichloroethylene (TCE) as a model contaminant. A standard Fenton's system, a modified soluble iron system with a pulse input of hydrogen peroxide, and two

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