L511692

2:1 2,2′-Bipyridine:Cyclopentadienyl(n6-napthalene)ruthenium(II) hexafluorophosphate

Aldrich^CPR

• Synonym(e): Herzon Hydration Catalyst
• Empirische Formel (Hill-System): C₂₅H₂₁N₂Ru · PF₆
• Molekulargewicht: 595.48
• UNSPSC-Code: 12352200
• PubChem Substanz-ID: 329817529

Eigenschaften

• SMILES String: F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=CC=CC=N1.C3(C4=NC=CC=C4)=CC=CC=N3.[C]56[C][C][C][C][C]5C=CC=C6.[Ru+].[C]7[C][C][C][C]7
• InChI: 1S/2C10H8N2.C10H8.C5H5.F6P.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-2-6-10-8-4-3-7-9(10)5-1;1-2-4-5-3-1;1-7(2,3,4,5)6;/h2*1-8H;1-8H;1-5H;;/q;;;;-1;+1
• InChIKey: YFGQTOCRCOVSBH-UHFFFAOYSA-N

Beschreibung

Anwendung

Ready mixed, single catalyst system developed by the Herzon Group for terminal alkyne functionalization. Used recently by that group to affect the anti-Markovnikov reductive hydration alkynes.

Temporal separation of catalytic activities allows anti-Markovnikov reductive functionalization of terminal alkynes

Sonstige Hinweise

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Sicherheitshinweise

• Piktogramme: GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H302,H318
• P-Sätze: P280 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Eye Dam. 1
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable