A88476

4-Methoxy-benzoylchlorid

99%

• Synonym(e): p-Anisoylchlorid
• Lineare Formel: CH₃OC₆H₄COCl
• CAS-Nummer: 100-07-2
• Molekulargewicht: 170.59
• Beilstein: 471918
• EG-Nummer: 202-816-4
• MDL-Nummer: MFCD00000687
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24891375
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 99%
• Form: liquid
• Brechungsindex: n20/D 1.581 (lit.)
• bp: 262-263 °C (lit.)
• mp (Schmelzpunkt): 22 °C (lit.)
• Dichte: 1.260 g/mL at 20 °C (lit.)
• SMILES String: COc1ccc(cc1)C(Cl)=O
• InChI: 1S/C8H7ClO2/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5H,1H3
• InChIKey: MXMOTZIXVICDSD-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

4-Methoxybenzoyl chloride is one of the reactive acylating agents that can react with carboxylic acids, alcohols and amines to yield respective carboxylic anhydrides, esters and amides.

4-methoxybenzoyl chloride reacts with potassium thiocyanate to yield isothiocyanate derivative via nucleophilic addition-elimination mechanism.

Anwendung

• 4-Methoxybenzoyl chloride can be used as radical precursor in visible-light photocatalysis to synthesize various heterocyclic compounds.
• It can be used to synthesize acylphosphine ligands for the rhodium-catalyzed hydrosilylation of alkenes.
• Incorporation of 4-methoxybenzoyl chloride modified indium tin oxide (ITO) as cathode for the fabrication of organic light-emitting diodes (OLEDs) has been reported.
• 1,3 diketones synthesized from 4-methoxybenzoyl chloride can be used in one pot synthesis of various pyrazole derivatives.
• It can also be used in the total synthesis of bioactive compounds like echinoside A and salinosporamide A.

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310
• Gefahreneinstufungen: Eye Dam. 1 - Skin Corr. 1B
• Zusätzliche Gefahrenhinweise: EUH014
• Lagerklassenschlüssel: 8A - Combustible, corrosive hazardous materials
• WGK: WGK 1
• Flammpunkt (°F): 188.6 °F - closed cup
• Flammpunkt (°C): 87 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter