908541

Ni(IPr*OMe)(phenyl acrylate)₂

• Synonym(e): Montgomery Ni catalyst
• Empirische Formel (Hill-System): C₈₇H₇₂N₂NiO₆
• CAS-Nummer: 2230140-52-8
• Molekulargewicht: 1300.21
• MDL-Nummer: MFCD31747048
• UNSPSC-Code: 12352103
• NACRES: NA.22

Eigenschaften

• Form: powder
• Eignung der Reaktion: reagent type: catalyst; reaction type: Cross Couplings
• SMILES String: [Ni].N8(CN(C=C8)c9c(cc(cc9C(c%13ccccc%13)c%12ccccc%12)OC)C(c%11ccccc%11)c%10ccccc%10)c3c(cc(cc3C(c7ccccc7)c6ccccc6)OC)C(c5ccccc5)c4ccccc4.O(c2ccccc2)C(=O)C=C.O(c1ccccc1)C(=O)C=C
• InChI: 1S/C69H58N2O2.2C9H8O2.Ni/c1-72-58-45-60(64(50-27-11-3-12-28-50)51-29-13-4-14-30-51)68(61(46-58)65(52-31-15-5-16-32-52)53-33-17-6-18-34-53)70-43-44-71(49-70)69-62(66(54-35-19-7-20-36-54)55-37-21-8-22-38-55)47-59(73-2)48-63(69)67(56-39-23-9-24-40-56)57-41-2
• InChIKey: CYALLPYVCSBFMX-UHFFFAOYSA-N

Beschreibung

Anwendung

Ni(IPr*OMe)(phenyl acrylate)₂ is an NHC-Ni(0) precatalyst developed in the Montgomery lab used for a variety of synthetic transformations including reductive couplings of aldehydes and alkynes and N-arylation of amines.

Sonstige Hinweise

Stable, Well-Defined Nickel(0) Catalysts for Catalytic C–C and C–N Bond Formation

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable