902144

[(Cp)Ru(η⁶-naphthalene)]OTf

≥95%

• Synonym(e): (η⁵-Cyclopentadienyl)(η⁶-naphthalene)ruthenium(1+) trifluoromethanesulfonate
• Empirische Formel (Hill-System): C₁₆H₁₃F₃O₃RuS
• CAS-Nummer: 811794-35-1
• Molekulargewicht: 443.40
• UNSPSC-Code: 12352101

Eigenschaften

• Assay: ≥95%
• Form: powder
• Eignung der Reaktion: reagent type: catalyst; reaction type: C-C Bond Formation
• mp (Schmelzpunkt): 112-116 °C
• Lagertemp.: 2-8°C

Beschreibung

Anwendung

Stable precursor for synthesis and ruthenium catalysis. It was also used by the Ritter lab to synthesize an Fmoc-protected ruthenium tyrosine for subsequent incorporation of the [18F]fluoride radiolabel into polypeptides.

Sonstige Hinweise

Site-Specific Deoxyfluorination of Small Peptides with [18F]Fluoride

Comparison of the Catalytic Activity of [(5-C5H5)Ru(2,2′-bipyridine)(L)]OTf versus [(5-C5H5)Ru(6,6′-diamino-2,2′-bipyridine)(L)]OTf (L = labile ligand) in the Hydrogenation of Cyclohexanone. Evidence for the Presence of a Metal–Ligand Bifunctional Mechanism under Acidic Conditions

Arene Exchange in the Ruthenium-Naphthalene Complex [CpRu(C10H8)]+

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable