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743003

Sigma-Aldrich

2-Butanonperoxyd

technical

Synonym(e):

Bis-(1-hydroperoxy-1-methylpropyl)-peroxid, Ethyl-methylketon-peroxid

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About This Item

Lineare Formel:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
CAS-Nummer:
1338-23-4
Molekulargewicht:
210.22
Beilstein:
1759757
MDL-Nummer:
MFCD00042641
UNSPSC-Code:
12352120
PubChem Substanz-ID:
329765606
NACRES:
NA.22

Qualität

technical

Form

liquid

Enthält

2,2,4-trimethyl-1,3-pentanediol-diisobutyrate as stabilizer

Eignung der Reaktion

reagent type: oxidant

Brechungsindex

n20/D 1.432

Dichte

1.053 g/mL at 20 °C (lit.)

Funktionelle Gruppe

hydroperoxide
peroxide

Lagertemp.

2-8°C

SMILES String

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

InChIKey

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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Anwendung

Reactant for:
  • Studies of the adiabatic runaway reaction of Me Et Ketone peroxide
  • Quantitation of metal ions in archaeological glass via abrasive stripping square-wave voltammetry
  • Imaging of hydrogen peroxide and hydrogen peroxide-scavenging substances by photon emission
  • Synthesis of oligonucleotides via phosphoramidite method
  • Oxidation of nucleoside phosphites into phosphates
  • Comparing the relative effectiveness of human plasma glutathione peroxidase as a catalyst for reduction of hydroperoxidases

Analyte for direct electrochemical catalystis of immobilized Hb in an ethanol-water mixture

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Flam. Liq. 3 - Org. Perox. D - Skin Corr. 1B

Lagerklassenschlüssel

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 1

Flammpunkt (°F)

132.8 °F - closed cup

Flammpunkt (°C)

56 °C - closed cup

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
BCCF7634
BCCB0718
BCBV4363
BCBV2664
BCBG4416V

Die passende Version wird nicht angezeigt?

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Cumolhydroperoxid technical grade, 80%

Sigma-Aldrich

247502

Cumolhydroperoxid

Luperox® A75, Benzoylperoxid 75%, remainder water

Sigma-Aldrich

517909

Luperox® A75, Benzoylperoxid

Dicumylperoxid 98%

Sigma-Aldrich

329541

Dicumylperoxid

2-Butanon Pharmaceutical Secondary Standard; Certified Reference Material

Supelco

PHR1207

2-Butanon

F T Fraunfelder et al.
American journal of ophthalmology, 110(6), 635-640 (1990-12-15)
Methyl ethyl ketone peroxide is a commonly used catalyst in various industries. We studied 19 eyes with a single exposure to methyl ethyl ketone peroxide that developed clinical patterns of mild injury, moderate injury, severe injury, or delayed keratitis. Delayed
M Ando et al.
Toxicology and applied pharmacology, 81(3 Pt 1), 517-524 (1985-12-01)
Some new aspects of damage to cytochrome P-450 peroxidase activities by a toxic peroxide were investigated. Methyl ethyl ketone peroxide (MEKP) damage to cytochrome P-450 and inhibition of cytochrome P-450-mediated peroxidase activities were studied. In vivo, hepatic microsomal NADH- and
M Ando et al.
Chemico-biological interactions, 55(3), 317-326 (1985-11-01)
The effect of dietary vitamin E on in vivo and in vitro damage by methyl ethyl ketone peroxide (MEKP) to cytochrome P-450 and its associated enzymatic activity was studied. In vivo, MEKP damaged microsomal cytochrome P-450 and cytochrome P-450-mediated peroxidases
Jing Zhang et al.
Journal of hazardous materials, 181(1-3), 1024-1030 (2010-06-18)
Methyl ethyl ketone peroxide (MEKPO) is widely used in polymer industry. It is highly sensitive to heat, friction, shock, flame or other sources of ignition, causing risks in production, storage and transportation. In this article, MEKPO is synthesized at a
M N Bozdemir et al.
Human & experimental toxicology, 30(12), 2002-2006 (2011-04-22)
Although ingestion of methyl ethyl ketone peroxide (MEKP) is rare, it carries a high risk of morbidity and mortality. This paper reports the first such case from Turkey in which a 70-year-old man unintentionally ingested MEKP in his kitchen. The
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